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Journal of Structural Chemistry

2015 year, number 6

ON THE POSSIBILITY OF COLLECTIVE VORTEX MOTION IN LIQUIDS

V. P. Voloshin1, Yu. I. Naberukhin1,2
1Voevodsky Institute of Chemical Kinetics and Combusetion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: жидкости, вода, жидкий аргон, молекулярная динамика, коллективные эффекты, вихревые движения

Abstract

It is shown that a model system of random walk of particles with superimposed vortex motion simulates the specific behaviors of a two-particle correlation function DP ( t ) = <[r i ( t ) - r i (0)]×[r k ( t ) - r k (0)]>, which are observed in molecular dynamics models of water and liquid argon. Hence, in liquids there well may be mesoscopic-sized vortices (of the order of ten intermolecular distances).