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Journal of Structural Chemistry

2015 year, number 5

CRYSTAL STRUCTURE OF THE INCLUSION COMPOUND OF A POROUS METAL-ORGANIC POLYMER WITH 2-CYCLOPENTENE-1-ONE

I. S. Khan1,2, D. G. Samsonenko1,2, V. P. Fedin1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: кристаллическая структура, пористые координационные полимеры, соединение включения, цинк, crystal structure, porous coordination polymers, inclusion compounds, zinc

Abstract

The inclusion compound of the composition [Zn 2(dmf)(bdc)(lac)]×C 5H 6O is obtained by keeping a porous homochiral metal-organic polymer of the composition [Zn 2(dmf)(bdc)(lac)]·DMF (DMF = N,N-dimethylformamide, H 2bdc = terephthalic acid, H 2lac = S -lactic acid) in liquid 2-cyclopentene-1-one, and the crystal structure of the compound is determined.