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Avtometriya

2013 year, number 6

9921.
Hilbert Diagnostics of Phase Disturbances of the Light Field Induced by a Vortex Flow

V. A. Arbuzov1,2, Yu. N. Dubnishchev1,2, V. G. Nechaev2, O. N. Novoselova2, D. S. Pechkin2, V. V. Sotnikov1,2, E. O. Shlapakova2
a:2:{s:4:"TEXT";s:256:"1Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 1, Novosibirsk, 630090 Russia
2Novosibirsk State Technical University, pr. Karla Marksa 20, Novosibirsk, 630073 Russia";s:4:"TYPE";s:4:"html";}
Keywords: optical diagnostics of flows, Hilbert optics, large-scale vortex structures, vortex rings
Subsection: PHYSICAL AND TECHNICAL PRINCIPLES OF MICRO- AND OPTOELECTRONICS

Abstract >>
Methods of Hilbert filtration of phase disturbances of the light field in the spectral range of source emission are discussed. The evolution of complementary vortex rings induced in an air medium by a pressure pulse on the hole in the combustor wall under various boundary and initial conditions is experimentally studied.



9922.
Cellular Automata Model of an Artificial Biological Cell in the Form of a Self-Replicating Structure

S. M. Achasova
a:2:{s:4:"TEXT";s:169:"Institute of Computational Mathematics and Mathematical Geophysics, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 6, Novosibirsk, 630090 Russia";s:4:"TYPE";s:4:"text";}
Keywords: cellular automata, self-replicating loop, parallel substitution algorithm, artificial biological cell
Subsection: MODELING IN PHYSICAL AND TECHNICAL RESEARCH

Abstract >>
Two cellular automata models of an artificial biological cell, which can be elements of computing devices that mimic the properties of living organisms (growth, self-reproduction, and selfrepair), are presented. The models are based on the parallel substitution algorithm, which is a spatial model for representing fine-grained parallel algorithms and architectures. An artificial biological cell is constructed from a genome applied to the input tape of the cellular automata structure. The result is a model of an artificial biological cell, which contains a phenotype as a set of fixed data and a genotype as a set of mobile data.



Scientific journal “Vestnik NSUEM”

2013 year, number 4

9923.
MODERN RUSSIAN TRENDS OF SPATIAL DEVELOPMENT AND REGIONAL POLICY AGAINST THE BACKGROUND OF WORLD TRENDS

V.E. Seliverstov
Keywords: Russia, spatial development, regional policy
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The article considers the genesis of spatial development and regional policy of post-Soviet Russia in the 1990s and the first decade of the new millennium. The specifics of the Russian transformations are revealed on the basis of comparison with world trends; disadvantages and problem fields are revealed; ways of development are shown.



9924.
MACROECONOMIC INDICATORS OF THE DEVELOPMENT OF THE SIBERIAN FEDERAL DISTRICT

A.A. Kiselnikov, I.V. Scherbak
Keywords: Siberian Federal District, gross regional product, key branches of economy, standard of living
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The report examines the results of the development of the Siberian Federal District in terms of macroeconomic indicators calculated at the regional level, such as gross regional product, the parameters characterizing a standard of living of the population, etc. In detail a condition and dynamics of key branches of economy of the territory are reflected. This paper estimates the contribution of the district to economy of the Russian Federation, the level of its economic and social development in comparison with other federal districts, the situation in the subjects of the Russian Federation which are a part of Siberian federal district. The conclusions and recommendations are drawn. As an information base of research used data from the state statistics.



9925.
REGIONAL CONSOLIDATION, COMPETITIVENESS AND DECENTRALIZATION OF CENTRAL AND EASTERN EUROPE IN R&D

Horvath Gyula
Keywords: Competitiveness, regional policy, research and innovation
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The article discusses the issues and modern trends of the regional policy implementation in countries of European Community (EC); the research is focused on one of the pressing directions suggested by the European Commission to increase competitiveness of EU in the global world – research and innovation; the estimate of the state and outlook of R&D in the regional section in countries of Central and Eastern Europe is given; comparative analysis is carried out; conclusions are drawn and recommendations are made.



9926.
REGIONALIZACION IN THE WESTERN BALKAN COUNTRIES BETWEEN WISHES, OPPORTUNITIES AND ILLUSIONS

Adžić Sofia
Keywords: Western Balkans, spatial cohesion, regionalization as a factor of economic development, regional, sub-regional and local policy
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The following study focuses on the analysis of the role of regionalization in restoring propulsive development in the Western Balkans. The following paper is based on the hypothesis that regionalization (statistical, administrative, political or any mix of them) only makes sense if it is put to use creating the conditions for spatial cohesion. Its mission is to unify the efforts of sub-regions and local governments to mobilize the resources providing conditions for: (1) export business and private (productive) investment, (2) labor and (3) life in general. In the context of this hypothesis, the paper is divided into three parts. The first part deals with the constitution of framework for reforming regional and local policies, based on the request that their main task is to put all of their resources into economic and development function. The second part deals with the key issues and controversies of the application of the mechanism of public-private partnership (PPP) projects to overcome the consequences of regional, sub-regional and local transitional depression. The third section discusses the role of regionalization in the formation and development of optimal dynamic combination of three basic production and organizational models of modern industry (Clusters, Industrial districts, Poles of generic growth). A key result is that the main task of the (economic) regionalization is to constitute adequate network of regional generic growth poles. The development of (regional) generic growth pole growth by creating an internationally competent staff and generating innovation, leads to opening space for rehabilitation development functions of related industrial districts and small and medium industrial centers.



9927.
ECOSYSTEM: A NEW MODEL OF COMPANY’S INTERACTION WITH EMPLOYEES, CUSTOMERS AND PUBLIC

I.D. Kotliarov
Keywords: employees, customers, public, externalization, internalization
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The present paper contains an analysis of modern forms of interaction between companies and employees, customers and public. It is demonstrated that quasi-internalization and quasi-externalization also apply to company’s cooperation with physical persons. A part of these persons are in transition between internal and external environment. This category of persons can be considered as company’s ecosystem



9928.
ORGANIZATIONAL AND ECONOMIC MECHANISMS OF REALIZATION OF MASTER TARGET TRAINING FOR INNOVATION ECONOMICS

S.S. Malina
Keywords: target training, network form, knowledge economy, inter-university interaction, state order
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The paper is devoted to questions of providing innovation economics with high-qualified specialists, to forms of the state support to the higher school, to mechanisms of the state order. The Region’s experience in realization of inter-university interaction in developing and implementation of Master programs is observed. The key aspects of the programs of target contractual training of masters are discussed in the paper. The results of the survey of the employers, engaged in implementation of the target contractual master training program, are presented and analyzed. The paper contains conclusions.



9929.
ALTERNATIVE CHOICE POLICY OF NATIONAL EGOISM: SOCIO-ECONOMIC CONSENSUS

A.S. Likhonosova
Keywords: Leadership, personal benefit, national interests, social values, the impact, priority, rational, sustainable development, selfishness
Subsection: SOCIETY AND ECONOMY: PROBLEMS OF DEVELOPMENT

Abstract >>
The study is the author's vision of national self-interest as a catalyst for national consciousness and, therefore, the development of patriotic attitude to the problems and prospects of the nation. Characterized by positive and negative aspects of national egoism and its consequences. The behavior of the modern Ukrainian government on the introduction of "policy of national self-interest". Substantiates the need for Ukraine to new standards of economic behavior on the principles of moral comparison of personal interests and social values. The basic economic consequences for Ukraine's active implementation of the principles of selfish behavior in the international arena.



9930.
TO THE QUESTION OF NEED OF FORMATION OF THE SCIENTIFIC THEORY OF AUDIT

P.P. Baranov
Keywords: Historical and economic preconditions of emergence of audit, interdisciplinary communications of audit, key problems of theoretical design of auditor scientific knowledge, question of existence of auditor science, reason of institutional insolvency of audit, subject and method of audit, form and structure of scientific knowledge
Subsection: FINANCE, ACCOUNTING AND ANALYSIS

Abstract >>
The hypothesis is formulated and locates in article that absence of academically issued scientific theory of audit is a factor provoking doubts in an institutional solvency of auditor activity. The arguments proving imbalance and separate nature of existing provisions of science about audit as systems of scientific knowledge are adduced. The conclusion about need of carrying out complex, including the interdisciplinary researches directed on cultivation of the scientific theory of audit as to organized area of economic science is drawn. Basic system problems of theoretical design of auditor science are formulated, the key problems interfering its formation reveal. The points of view of various schools of sciences on structure, mutual correlation and the content of the main attributes of the scientific theory of audit are characterized and are critically estimated; on the basis of the analysis of experience of foreign and domestic researches the directions of overcoming of the saved-up internal and external contradictions of auditor science and practice are offered.



9931.
STATISTICAL ANALYSIS OF MAIN SOCIAL-ECONOMIC INDICATORS OF THE ORENBURG REGION

V.N. Afanasjev
Keywords: Cycles, economic indicators, statistical methods of cycle analysis, cycle stability, statistical methodology of economic cyclisity research
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
The work presents the theoretical and methodological research basics of economic cyclicality, main classifications of economic cycles, research findings of cyclicality of social-economic indicators of Orenburg region economics by way of different statistical methods. The study was conducted with time series free from seasonal fluctuations and irregular component. Research of cycles in economics of the Orenburg region with regard to the trend has been done for the first time. Statistic basis of the research has been made up of official monthly data of Territorial body of Federal Agency of State Statistics in the Orenburg region in 1995-2012.



9932.
STATISTICAL ASPECT OF INVESTIGATION OF PURCHASING FUNCTION OF COOPERATIVE ORGANIZATIONS

T.G. Khramtsova
Keywords: Consumer cooperation, purchasing of agricultural products, grouping, variation, correlation-regression analysis
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
The article considers theoretical and methodical aspects of statistical investigation of purchasing function of cooperative organization: the industry value for economic activity and employment of rural sector is proved. The results of the statistical analysis of purchasing function of regional cooperative organizations are presented. It is demonstrated that subjective factors have key value for the development of procuring activities of cooperative organization.



9933.
REGIONAL SPECIFIC FEATURES OF DEVELOPMENT OF THE KEY FACTORS FOR AGRICULTURAL INDUSTRY IN THE REPUBLIC OF KAZAKHSTAN

A.P. Avrov, G.K. Sabyrova
Keywords: Yield, trend, variability, simultaneity, variation, correlation
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
The work gives consideration to experience, challenges and findings of statistic researches of crops yield in the Republic of Kazakhstan over the last twenty years; in the work trends and patterns of variability simultaneity of main crops yield are defined; subjects of the republic are classified according to climatic conditions; historical dating back is conducted to the yield condition and dynamics according to the groups of the region parts; information basis of the research is made up of data from state statistics service; specific features of yield variation are pointed out according to the year, sphere and region type.



9934.
APPLICATION OF SAMPLING METHOD IN THE SOCIO-ECONOMIC STUDY

E.S. Shmarikhina
Keywords: Sampling method, population, quality of statistical information, coefficient of trust, limiting error of sampling, average sampling error, number of sampling
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
In the report some aspects of quality of statistical information are outlined. Sampling in social-economic researches is given ground to. The essence of direct and return problem of selection method is considered, terms are specified, formulas of calculation of an average and limit error of a sample average and a share are given. The importance of correction for finitude of population in social and economic researches when solving return problem of sampling is indicated. The procedure of payments of sampling number and assessment of indicators necessary for this purpose at preparation of sampling are discussed. The work points out the need for recalculation of coefficient of trust when processing collected data for specification of confidential probability with results of sampling extending on main population. Solution of return problem of sampling method is approved within research of population of the Novosibirsk region - Social support of population: the need for help and directions of support. "Repair" of sampling because of its shift on the age of respondents increased the actual number to 460 people. Values of the recounted coefficients of trust according to the features which were based upon at determination of the sampling number confirm high reliability of information on population.



9935.
STATISTICAL METHODS IN THE SOLUTION OF THE APPLIED PROBLEMS OF THE DEVELOPMENT OF TERRITORY

E.Y. Chemezova
Keywords: Differentiation, integral index, uniformity, multidimensional average, municipal districts, portfolio analysis, typology, growth point
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
The author presents his own identification methods of the similar types of territorial units in the report. Не deals with the preliminary considereation of the types, formation of informative signs and integral indices, specifics in the application of algorithms of typological group and portfolio analysis in the applied research of the development of territorial units, analysis for the groups of territorial units. The results of applied research in the region of social and economic division into districts are generalized. The paper also describes the methods of identification of sectoral “growth point” to work out the territorial units development strategy, based on the development of the matrix of portfolio analysis “The attractiveness of the region - competitivness” and identifies the intra-regional differentiation of municipal districts .It demonstrates the comprehensive typology of territorial units in the country, and also in the regions of Siberian federal territory, municipal districts in the Novosibirsk Oblast . The findings can be used for decision making in the restructuring of the economy in some regions, in the identification of economically depressed regions with the purpose of their economic and social development.



9936.
CLUSTER ANALYSIS IN HANDLING THE PROBLEM OF TYPOLOGY OF REGIONS OF RUSSIA BY LEVEL AND INTENSITY OF INTERNAL LABOR MIGRATION

E.S. Kovanova
Keywords: Migration, multidimensional classification, cluster analysis
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
Internal labor migration significantly affects the socio-economic development of regions of the country. The author carries out segmentation of territories by level and intensity of migration via cluster analysis. The emphasis is on “giving” regions. Official data of government statistics was used as a date base of the research. Conclusions are drawn, recommendations are made.



9937.
SPATIAL AND TIME APPROACH TO THE CONSTRUCTION OF PRODUCTION FUNCTIONS FOR SMALL ENTREPRENEURSHIP IN THE REGIONS OF RUSSIA

J.S. Pinkovetskaya
Keywords: Production function, spatial and panel data, small enterprises, turnover, investment, wage
Subsection: STATISTICS AND ECONOMIC DIMENSION

Abstract >>
The paper presents the methodical approaches and the results of construction the production functions, based on the use of spatial data for 2011 year and panel data for the period of 2007 year till 2011 year. Present functions, characterize the activity of the aggregation of small enterprises through the regions of the Russian Federation. Functions describes the dependence of turnover small enterprises from investment in fixed capital and wage of employees of these enterprises. Discuss the main characteristics of the achieved production function and their comparative analysis.



9938.
SOCIAL AND POLITICAL FACTORS OF CIVIL ACTIVITY IN RUSSIA

M.S. Kruglov
Keywords: Civil activity, political actors, social conditions, rallies, political actions, protest and political participation, values
Subsection: SOCIOLOGY

Abstract >>
The article examines the features of social and political factors of the development of civil activity in Russia, its role in political process of the Russian Federation. It examines the main values of Russian society, which provides several interconnected levels of civil participation with their inherent specific characteristics. Conclusions, made in the article, tell about the transformation of civil activity from the local level up to the protest and political participation in the period from 2005 to 2012, about the potential of forms of civil activity.



9939.
SOCIAL-ECONOMIC CONFLICTS IN A MODERN SOCIETY

E. A. Nedobega
Keywords: interests, conflict, society, development, social safety, social responsibility
Subsection: SOCIOLOGY

Abstract >>
In the report features of social-economic conflicts and their role in society development are considered by the example of Ukraine. Social-economic conflicts arise between participants of public administration, corporate relations and society as a result of distinctions in their interests and requirements. Unresolved conflicts result in decrease in level of social safety of the country. In order to make conflicts influece society development positively, it is necessary to adjust interaction between conflict parties through cooperation and to adhere to the principles of harmonization of interests and social responsibility.



9940.
ANALYSIS OF TARIFF POLICY IN PUBLIC WATER SUPPLY SUSTEM

V.N. Afanasjev, S.A. Zhuravlev
Keywords: municipal services tariffs, statistical analysis methods, tariff structure
Subsection: FACTS, APPRAISALS, PERSPECTIVES

Abstract >>
The report provides theoretical interpretation of main public tariff policy challenges in the Russian Federation based on the investigation of the content of tariff forming methods in the country and abroad, and on the analysis of methods and types of state and business structures in the form of private-public partnership; as a result of multidimensional statistical analysis of time series, structural differences, and causalities was proved faster growth of changing public water supply tariff compared to the nominal income growth, and high level of assets depreciation and direct influence of assets renewal on quality of public water supply and disposal services in Orenburg; cost managing methods were supplemented by improved structural analysis of costs on providing water supply and disposal services, of expert assessment of discovered statistical parameters which significantly influence tariff formation; by scheme and decision tree at the main stage of tariff formation – cost management; for the first time statistic tariff forecasting is conducted according to one-dimensional models of time series and results of multi-factor tariff modeling for the services rendered by Orenburg Vodokanal, OOO.



9941.
PERSONAL INCOME GENERATION AS SOCIAL SUBSYSTEM

L.N. Fyodorova
Keywords: income, social subsystem, structure, transformation, differentiation
Subsection: FACTS, APPRAISALS, PERSPECTIVES

Abstract >>
The structure of forming of the personal incomes is considered as hierarchical education, including totality of elements and functions, accomplished under influence of factors and institutes of society. The stages formative the vertical structure of process of forming of the personal incomes as a secondary subsystem of global frame of society are distinguished. The theoretical justification of the features of the object in terms of socio-economic transformation is given and the trends that influence the formation of personal income are described. The real trends of the transformational process are showing.



9942.
FORECASTING OF AGRICULTURAL ECONOMIC RISK BASED ON ITS DEVELOPMENT CYCLE

I.A. Ivanova
Keywords: food supply security, agricultural system, stability, agriculture, manufacture
Subsection: FACTS, APPRAISALS, PERSPECTIVES

Abstract >>
This article considers the research of agricultural system stability based on the observation of spatiotemporal common factors of agriculture development cyclicality as a main component of the food supply security system. With the help of the spectral analysis the mathematical model of forecasting was developed to demonstrate the cycling of events in the agricultural sector. This model is based on the dynamic series of grain yield level in the European part of Russian Empire, USSR and Russian Federation in its modern boundaries for the period from 1883 till 2010.



9943.
DOES MIGRATION LEAD TO REGIONAL CONVERGENCE IN RUSSIA?

E. S. Vakulenko
Keywords: convergence, income, migration, spatial dynamic panel data models, unemployment, wage
Subsection: FACTS, APPRAISALS, PERSPECTIVES

Abstract >>
We analyze the impact of migration on wage, unemployment rate and income. Using Russian official statistical database from 1995 to 2010 we estimate dynamic panel data model with spatial effects. There is no significant impact of migration on unemployment rate. There is a positive spatial effect for wage and unemployment. We find negative relationship between net internal migration, and both wage and income, which is explained by positive effect of out-migration on wage and income. However, the migration benefits are not big enough to make a difference on Gini index across regions. We conclude that migration does not affect regional convergence of economic indicators. This study was carried out within The National Research University Higher School of Economics’ Academic Fund Program in 2013-2014, research grant No. 12-01-0175.



9944.
EFFICIENCY AND EFFECTIVENESS OF USE OF INFORMATION SYSTEMS

E. Gerhardt, O. Bogdanov
Keywords: Reverse Business Engineering, Business-IT-Alignment, reverse engineering, business processes
Subsection: BUSINESS INFORMATICS

Abstract >>
The use of information systems in business implies on the one hand that IT-systems are constantly adapting to the requirements of the company as business processes are changing all the time. On the other hand business processes should be aligned with technical capacities of IT-systems as they develop very quickly. This approach is called Business-IT Alignment in IT management. Unfortunately the reality is there are significant gaps and weaknesses in the management and use of information systems. This leads to the decrease of efficiency and effectiveness of the business processes support. Reverse Business Engineering or to be more exact regular diagnostics used in the IT area can help to fill in the gap between business and IT by tracking transaction data, logfiles, and user behavior. This approach requires a comprehensive analysis of information systems to determine system modification, unused capacities, business process deviations, etc. So, fixing weaknesses that were found in this way in information systems and business processes improves dynamic business strategy support and increases competitiveness.



9945.
IT INFRASTRUCTURE HIGH SCHOOL AS A PLATFORM FOR THE DEVELOPMENT OF INFORMATION TECHNOLOGY

Z.D. Mamykova, G.M. Mutanov, L.K. Bobrov
Keywords: IT infrastructure, strategic management, information systems
Subsection: BUSINESS INFORMATICS

Abstract >>
The article is devoted to the formation of the IT infrastructure of the university. The development strategy of the IT infrastructure is presented as part of the overall IT strategy that focuses on effective information support core business processes of the University by processing of various information resources. Formulated requirements to its IT infrastructure, relevant Smart-society ideas. Describes the major components and discusses the idea of ​​advancing the development of the IT infrastructure.



9946.
ENEMIES OF THE EMPIRE. HISTORICAL COMPARATIVISTICS OF THE “RUSSIAN SOCIOLOGICAL SCHOOL”

Yu. P. Ivonin, O. I. Ivonina
Keywords: positivism, etatism, comparativistics, social evolution
Subsection: PHILOSOPHY, EXTERNAL RELATIONS, LAW

Abstract >>
The article analyzes the comparativistics of the most influential opposition union of Russian intellectuals of the 19th century – the “Russian sociological school”. The comparativistics included diachronic and synchronous aspect: comparison of development stages of domestic and Western European social organism and comparison of basic characteristics between Russia and Western Europe. It is demonstrated that the comparativistics was based on principles of radical socialism and antietatism that gradually lost the initiative to principle of liberalism.



9947.
THE ARABIAN SPRING: RETURNING TO SOURCES?

M.A. Kurbanov
Keywords: Islam, unemployment, youth, Egypt, Middle East monarchies, The USA
Subsection: PHILOSOPHY, EXTERNAL RELATIONS, LAW

Abstract >>
The article examines the events that began in the Arab East in the end of 2010. and entered history as the «Arab spring». Analyses the economic, socio - political and spiritual - moral reasons underlying these events: what were of paramount importance, and which were only background. This article also covers the various aspects of mutual relations of the United States of America and the Middle East countries, aims to analyze the role played in the recent events in the Arab world in General, the West and the USA.



9948.
THE IDEA OF «INTELLECTUAL ADULTHOOD» IN THE EUROPEAN CULTURE PARADIGM AND OPTIONS

G. M. Vasilyeva
Keywords: intelligence, reflection, paradigmatic characteristics, negative anthropology
Subsection: PHILOSOPHY, EXTERNAL RELATIONS, LAW

Abstract >>
The article attempts to reconstruct the idea of «intellectual adulthood» suggested by Kant. It is an adult personality that defines a fully-fledged tradition. This concept became the subject of culturological reflection in the works by Schopenhauer, Herzen, Spengler. It turned out to be constantly connected with Goethe’s artistic and scientific ideas. The idea interpretation of era, culture, person coming of age is based on the German classic’s apophatic concept.



9949.
ON ONE PARADOX OF PART-WHOLE RELATIONS

A.V. Yamushkin
Keywords: part, whole, part-whole relations, paradox in science, system sustainability
Subsection: PHILOSOPHY, EXTERNAL RELATIONS, LAW

Abstract >>
This article deals with one paradox of part-whole relations. Previously it has not been in the scientific literature on problems of part-whole relations and general questions of philosophy and philosophical questions of chemistry. Essence of this paradox has researched. Appropriate examples have provided.



9950.
INTERPRETIVE FUNCTION OF REFLEXIVE CONTROL AS DEVELOPMENT OF SYSTEMATIC DECISION-MAKING IN BUSINESS

E. V. Freydina, A.A. Botvinnik, A.A. Koroh
Keywords: cognitive map, cognitive function, empathetic strategy (E-strategy), interpretation function, interpretative approach, reflective management
Subsection: THEORETICAL SEARCH AND OFFERS

Abstract >>
The article dwells upon methodological aspects of developing the reflexive management control in socio-economic environments as a priority-oriented process toward the business-situation and problem situation and making the decision system´s. Constructed structure of interpreting function and identified one’s task, describe connection between the instruments of cognitive and interpreting functions. Generalized class’s models of making the decision in business. Model classes in interpreting function are systematisered.



9951.
MEASUREMENT OF THE BRAND POWER USING ICONIC ORIENTED GRAPHS

K.Y. Kazantsev
Keywords: the brand power, iconic oriented graphs, brand performance, factors of influence on the brand, cognitive model
Subsection: THEORETICAL SEARCH AND OFFERS

Abstract >>
The article considers the existing approaches to measuring of the brand power, special attention is paid to the analysis of existing mathematical models, which allow to estimate efficiency of branding company and quantify his power. Based on the analysis of models a list of the factors having impact on the brand is drawn up, and a cognitive model of the influence of different factors on the strength of a brand is composed of, as well as their mutual influence on each other. Based on the method of iconic oriented graphs presents the trend of influence of various factors of brand strength in time.



9952.
DEVELOPMENT OF REGIONAL RESOURCE SUPPORT CENTRES OF SOCIALLY ORIENTED NONCOMMERCIAL ORGANIZATIONS: ISSUES AND OUTLOOK

A.V. Isaev
Keywords: regional resource center, socially oriented non-profit organization, further education students, the problems of development of supplementary education
Subsection: THEORETICAL SEARCH AND OFFERS

Abstract >>
The implementation of additional educational programs students and young people is one of the most important tasks of any society. Fixing socially acceptable behavior algorithms members of society significantly reduces the growth of social tensions and the risk of social conflicts in society. Option for the development of additional education is the creation of regional resource centers to support socially oriented non-profit organizations.



9953.
ASSESSING THE NEED TO IMPROVE ACTIVITIES OF TRADING ENTERPRISES BASED ON THE IMPLEMENTATION OF QUALITY MANAGEMENT SYSTEM

O.V. Dyudina
Keywords: process, development, assessment, level of maturity, quality management system
Subsection: THEORETICAL SEARCH AND OFFERS

Abstract >>
Implementation of quality management system in the activities of trading enterprises - is one of the tools to improve the organization and functioning of the processes, which is currently not developed in relation to the trading industry. But not all enterprises require in this approach of development activities. The proposed method of assessing the need for the development of trading enterprises through the implementation of a quality management system will allow trading enterprises to orient in the direction of improvement.



2013 year, number 6

9954.
Description of spin-crossover in a heterogeneous chain of exchangE clusterS

V. A. Morozov
International Tomography Center, Siberian Division, Russian Academy of Sciences, Novosibirsk
Keywords: molecular magnetics, exchange cluster, spin-crossover, effective magnetic moment

Abstract >>
Spin transition theory is developed for periodic chains with two and more exchange clusters in a unit cell. A general expression is obtained for the effective magnetic moment of a unit cell μeff with several exchange clusters. For heterospin complexes Cu(hfac)2LR characterized by chains with the head-to-head motif a two-site approximation for the statistical sum of the Cu2+ Jahn – Teller paramagnetic center Cu2+ with spin 1/2 is proposed, within which a comparison with the available experimental data is performed. It is shown that the model developed describes both smooth and abrupt (cooperative) spin-crossover cases for the chains of three-spin exchange clusters.



9955.
ELECTRONIC STRUCTURE AND RELATED PROPERTIES FOR QUASI-BINARY (GaP)1– x(ZnSe)x CRYSTALS

W. Kara Mohamed1, F. Mezrag2, M. Boucenna2, N. Bouarissa3,4
1University of Bordj-Bou-Arreridj, El-Anasser, Bordj-Bou-Arreridj, Algeria
2University of M'sila, M'sila, Algeria
3College of Science and Arts Najran University, Najran, Saudi Arabia
4Centre for Advanced Materials and Nano-Engineering (CAMNE) Najran University, Najran, Saudi Arabia
Keywords: electronic structure, optical properties, quasi-crystals, pseudopotentials

Abstract >>
The results of pseudopotential calculations of the band structure and related electronic and optical properties of quasi-binary (GaP)1– x(ZnSe)x crystals in the zinc blende structure are presented. Trends in bonding and ionicity are discussed in terms of electronic charge densities. Moreover, the composition dependence of the refractive index and dielectric constants are reported. The computed values are in reasonable agreement with experimental data. The results suggest that for a proper choice of the composition x , (GaP)1– x(ZnSe)x could provide more diverse opportunities to achieve the desired electronic and optical properties of the crystals which would improve the performances of devices fabricated on them.



9956.
INSIGHT INTO THE CHEMICAL BONDING AND ELECTROSTATIC POTENTIAL: A CHARGE DENSITY STUDY ON A QUINAZOLINE DERIVATIVE

A. Tojiboev1, R. Wang2, F. Pan2, U. Englert2, K. Turgunov3, R. Okmanov3
1Namangan State University, Namangan, Uzbekistan
2Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen, Germany
3S.Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Uzbekistan, Tashkent, Uzbekistan
Keywords: quinazoline, electronic structure, high-resolution X-ray diffraction, charge density, topological analysis, dipole moment

Abstract >>
2,3-Trimethylene-3,4-dihydroquinazoline shares the heterocyclic core with natural compounds and synthetic drugs. The hydrochloride of the compound forms excellent dihydrate crystals which have allowed us to collect high-resolution X-ray diffraction data and obtain the experimental charge density. The solid may be understood as built up from pairs of heterocyclic cations and chloride anions; a direct hydrogen bond links the halide to the formally cationic pyrimidine NH group. The hydrate water molecules interact with the anions, forming an infinite chain along the crystallographic a axis between the stacks of the heterocyclic cations. Based on the experimental charge density, a dipole moment of 16.1 Debye is calculated for a pair of the hydrogen-bonded quinazolinium cation and the chloride anion in the extended crystal structure.



9957.
THEORETICAL STUDY OF HYDROPHOBICITY AND HYDROPHILICITY OF INDOLE, SKATOLE, AND ETHANOLE

G. N. Ten1, A. A. Yakovleva1, V. I. Baranov2
1N. G. Chernyshevsky Saratov State University, Saratov
2V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow
Keywords: indole, skatole, ethanole, complexes with water, hydrophobicity, geometric parameters of the hydrogen bridge, stretching vibrational frequencies

Abstract >>
The structures of indole, skatole, and ethanole complexes with water molecules are calculated by the DFT method. Radial and angular dependences of hydrogen bridge parameters on the number of water molecules are analyzed. Two models are determined which enable the study of the reason for the hydrophobicity of indole and skatole. Frequencies and intensities of absorption bands corresponding to stretching vibrations of the NH bond of indole, skatole, and ethanol in complexes with water are compared. It is shown that the main reason for the domination of the hydrophobic component over the hydrophilic one is the taking into account of the interaction of water molecules with the aromatic system of indole and skatole, finally resulting in a substantial decrease in the HB strength.



9958.
Intramolecular hydrogen BOND С–Н···N in 1,1'-divinyl-2,2'-diimidazolyl According to the data of аb initio calculations and QTAIM analysis

A. V. Vashchenko, A. V. Afonin
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk
Keywords: intramolecular hydrogen bonds С–H···N, ab initio calculation, QTAIM, RDG analysis

Abstract >>
By non-empirical ab initio quantum chemical calculation the spatial structure of 1,1'-divinyl-2,2'-diimidazolyl is determined and the formation of intramolecular hydrogen bonds of the С–H···N type in it is established. It is evidenced by energy preference for the conformation in which there is a short contact between the α-proton of the vinyl group and the endocyclic nitrogen atom (2.28 Å), creating favorable conditions for the formation of a six-membered chelate cycle. An analysis of the topological characteristics of the electron density and the reduced electron density gradient also give evidence in favor of the formation of a weak intramolecular hydrogen bond C–H···N. The estimation of the hydrogen bond energy by the Espinosa method results in a value below 3 kcal/mol.



9959.
Synthesis of mesoporous bimetallic Pt–Sn catalytic coatings from polynuclear precursors for fine organic synthesis processes

L. B. Okhlopkova1, E. V. Matus1, I. Z. Ismagilov1, M. A. Kerzhentsev1, I. P. Prosvirin1, Z. R. Ismagilov2
1G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
2Institute of Coal Chemistry and Chemical Materials Science, Siberian Division, Russian Academy of Sciences, Kemerovo
Keywords: capillary microreactors, nanostructured catalysts, mesoporous titanium oxide, sol-gel synthesis, bimetallic clusters, citral hydrogenation

Abstract >>
A new method is developed to obtain nanosized catalytic Pt–Sn/TiO2 coatings on the inner surface of a capillary microreactor during adsorption of polynuclear carbonyl Pt–Sn complexes on mesoporous TiO2. Titanium oxide sol prepared in the presence of template (Pluronic F127 surfactant) is supported in dynamic mode. Pt–Sn bimetallic catalysts with an average particle size of 1.5-2 nm are synthesized by adsorption of the bimetallic [Pt3(CO)3(SnCl3)2(SnCl2×H2O)]n2n¯ complex followed by thermal treatment. Physicochemical properties of samples (thickness, structure and morphology, chemical composition of the material, electronic state, specific surface area, pore volume and size distribution) are characterized by a set of methods (HR TEM, SEM, powder XRD, XRF, XPS, low-temperature nitrogen adsorption). Conditions to prepare the uniform non-peelable Pt–Sn/TiO2 coating on the inner surface of a silica capillary with good adhesion are determined. To increase the TiO2 thickness, multilayered TiO2 films are synthesized by layer-by layer deposition. The coating thickness is found to increase with an increase in the capillary diameter. The coating of a capillary with a diameter of 0.55 mm after 14-fold deposition is characterized by a thickness of 2 mm and an average pore size of 5.4 nm. The solvent effect on the adsorption of Pt–Sn carbonyl complexes into the TiO2 support is studied. The amount of the adsorbed complex increases in the following order: ethanol < acetone ~ tetrahydrofuran. The physicochemical properties of the active component (surface concentration, dispersion, and composition) can be fine-tuned by varying the deposition method, precursor concentration in the initial solution, and temperature conditions of activation treatment. The catalyst activity in citral hydrogenation was 0.06-0.54 min–1, with the selectivity with respect to unsaturated alcohols reaching 90% at citral conversion above 95%.



9960.
DFT, FT-RAMAN, AND FT-IR INVESTIGATIONS OF 1-CYCLOPROPYLPIPERAZINE

G. Keşan1, O. Alver2, M. Bilge3, C. Parlak4
1University of South Bohemia, České Budĕjovice, Czech Republic
2Anadolu University, Eskişehir, Turkey
3Ege University, İzmir, Turkey
4Dumlupınar University, Kütahya, Turkey
Keywords: 1-cyclopropylpiperazine, vibrational spectra, PED, DFT, B3LYP

Abstract >>
FT-IR and FT-Raman spectra of 1-cyclopropylpiperazine (1cppp) are experimentally examined in the range 4000—200 cm–1. The optimized geometric parameters, conformational equilibria, normal mode frequencies and corresponding vibrational assignments of 1cppp C7H14N2 are theoretically examined by means of B3LYP hybrid density functional theory (DFT) with the 6-31++G(d,p) basis set. Based on the potential energy distribution (PED) reliable vibrational assignments are made and the thermodynamics functions, highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO) of 1cppp are predicted. Calculations are performed for four different conformations in two point groups of 1cppp in the gas phase. A comparison between the experimental and theoretical results indicates that the B3LYP method is able to provide satisfactory results for the prediction of vibrational frequencies, structural parameters, and assignments. Furthermore, the C s (equatorial-equatorial) point group is found as the most stable conformer of 1cppp.




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