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Journal of Mining Sciences

2015 year, number 5

Sulfhydryl Phosphorus-Containing Collectors in Flotation of Copper-Nickel Platinum-Group Metals

V. A. CHANTURIA, A. A. LAVRINENKO, L. M. SARKISOVA, T. A. IVANOVA, N. I. GLUKHOVA, E. A. SHRADER, I. V. KUNILOVA
Research Institute of Comprehensive Exploitation of Mineral Resources-IPKON Russian Academy of Sciences, Kryukovskii tupik 4, Moscow, 11120 Russia
Keywords: Медно-никелевая руда, пирротин, пентландит, платиновая чернь, фосфорсодержащие сульфгидрильные собиратели, диизобутилдитиофосфинат натрия, флотация, электродный потенциал, гидрофобность поверхности, адсорбция, copper-nickel ore, pyrrhotine, pentlandite, platinum black, sulfhydryl phosphorus-containing collectors, sodium di-isobutyl dithiophosphinate, flotation, electrode potential, surface hydrophobicity, adsorption

Abstract

The analysis involves influence of sulfhydryl phosphorus-containing collectors (SPC) on flotation of copper-nickel ore bearing metals from platinum group. Efficiency of SPC and butyl xanthate combination is illustrated, and their optimal ratio is determined. The authors study influence of the test agents on electrode potential and hydrophobic behavior of pyrrhotine, pentlandite and platinum black. UV and IR spectrophotometry has shown origination of disulfide di-isobutyl dithiophosphinate on the surface of pyrrhotine.