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Journal of Mining Sciences

2015 year, number 3

Complexing Collecting Agent for Selective Flotation of Chalcopyrite

I. G. ZIMBOVSKY1, T. A. IVANOVA1, V. A. CHANTURIA1, E. L. CHANTURIA2
1Research Institute of Comprehensive Exploitation of Mineral Resources-IPKON, Russian Academy of Sciences, Kryukovskii tupik 4, Moscow, 11120 Russia
2College of Mining, National University of Science and Technology-MISiS, Leninskii pr. 6, Moscow, 119991 Russia
Keywords: sulfide selection, sorption, flotation, chalcopyrite, pyrite, extraction, reagents

Abstract

Under analysis is interaction between 1-phenyl-2,3-dimethylaminopyrazolone-5 (AMD) and copper in solution and on the surface of chalcopyrite. It is found that AMD experiences chemical adsorption on the surface of chalcopyrite as a compound with copper. Effect exerted on adsorption of AMD agent on copper sulfide by ammonium rhodanate (NH4CNS), introduced as an additional ligand, or its mixture with acetic acid is defined. Based on the analytical research and the analytical chemistry data, the type of adsorption on the surface of chalcopyrite is determined. The flotation tests on monomineral fraction of chalcopyrite and pyrite, and copper sulfide ore prove selectivity of AMD in separation of chalcopyrite and pyrite.