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Journal of Structural Chemistry

2015 year, number 2

HEAT CAPACITY, CONDUCTIVITY, AND STRUCTURAL CHANGES OF WATER–SODIUM DODECYLSULFATE–TRIETHANOLAMINE–1-PENTANOL-1,1,2,2-TETRAFLUORODIBROMOETHANE MICROEMULSIONS

D. V. Batov1,2, V. N. Kartsev3, S. N. Shtykov3
1Krestov Institute of Solutions, Russian Academy of Sciences, Ivanovo, Russia
2Ivanovo State University of Chemical Technology, Ivanovo, Russia
3Chernyshevsky Saratov State University, Saratov, Russia
Keywords: microemulsions, conductivity, isobaric heat capacity, temperature and concentration dependences

Abstract

Water–sodium dodecylsulfate–triethanolamine–1-pentanol–1,1,2,2-tetrafluorodibromoethane microemulsions of five compositions with different water–hydrocarbon ratios at a constant total surfactant+co-surfactant concentration of ~ 22 wt.% are obtained and their specific isobaric heat capacity and specific conductivity are measured. The temperature and concentration dependences of the mentioned properties of microemulsions are analyzed and interpreted from the standpoint of structural changes in the five-component system.