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Chemistry for Sustainable Development

2015 year, number 2

Effect of Carbon Nanomaterials on the Thermal Stability of Photochemically Hardened Polydimethylsiloxane Polymers Doped with These Nanomaterials

S. V. LUZGAREV1, M. V. SHERINA1, A. S. LUZGAREV1,2, T. B. TKACHENKO1, A. A. MOROZ1,2, YU. A. SHEVELEVA1, CH. N. BARNAKOV2, A. V. SAMAROV2
1Kemerovo State University, Ul. Krasnaya 6, ,Kemerovo 650043 (Russia)
2Institute of Coal Chemistry and Material Science, Siberian Branch of the Russian Academy of Sciences, Pr. Sovetskiy 18, Kemerovo 650000 (Russia)
Keywords: polydimethylsiloxane polymers, carbon nanomaterials, composite materials, hardening, photo- and thermochemical reactions

Abstract

Effect of carbon nanomaterial on the thermal stability of photochemically treated polydimethylsiloxane materials doped with this carbon nanomaterial was studied. It was demonstrated that even the introduction of a small amount of carbon nanomaterial into high-molecular polydimethylsiloxane rubber SKT causes a substantial increase in the thermal stability of photochemically hardened polymer during thermolysis both in the inert atmosphere and in the air. This is assumed to be connected with its participation in suppression of destruction processes. The mechanisms of thermal and photochemical processes taking place in the polymer matrix are proposed.