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Journal of Structural Chemistry

2014 year, number Приложение 2

CRYSTAL STRUCTURE OF [Cp3*Ir3S2]Cl{(H2O)(HSO4)(H2SO4)}В·CHCl3

P. A. Abramov1,2, A. V. Virovets1, M. N. Sokolov1,2
1Nikolaev Institute of Inorganic chemistry Siberian Branch of the Russian Academy of Science, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: iridium, sulfide, supramolecular associate, X-ray structural analysis

Abstract

Reaction of [Cp*IrCl2]2 with (Me3Si)2S in the presence of moisture leads to the formation of a triangular cluster [Cp3*Ir3S2]2+, which was isolated and characterized as supramolecular adduct [Cp3*Ir3S2]Cl{(H2O)(HSO4)(H2SO4)}·CHCl3 (1).