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Chemistry for Sustainable Development

2014 year, number 4

Modification of Polymers byВ В Nanodispersed Ceramic Particles

V. A. POLUBOYAROV1, Z. A. KOROTAEVA1, I. A. PAULI2, A. A. ZHDANOK1, and G. E. SELYUTIN3
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia)
E-mail: sanych@solid.nsc.ru
2Siberian State University of Communication Lines, Ul. Dusi Kovalchuk 191, Novosibirsk 630049 (Russia)
3Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Ul. K. Marksa 42, Krasnoyarsk 660049 (Russia)
Keywords: polymeric nanocomposites, nanodispersed ceramic powders, modifying, strengthening, near-surface phase, X-ray phase analysis, crystallinity
Pages: 385–392

Abstract

Research results of the effect of nanodispersed ceramic powders on properties of nanocomposites based on high pressure polyethylene are given. It has been shown that the addition of the nanodispersed modifiers SiC, TiO2 leads to grinding up polyethylene grains up to the sizes of less than 0.1 μm. Herewith, an increase of the density and fastness to rubbing of polyethylene is observed, as well as the decrease in gas permeability (in 1.5 times) and water vapour permeability (in 1.7 times).