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Journal of Structural Chemistry

2014 year, number 3

CRYSTAL STRUCTURES OF [Pd(NH3)3(NO2)][Rh(NH3)2(NO2)4] AND [PdEn2][Rh(NH3)(NO2)5]В·0.75H2O

S. P. Khranenko1, N. V. Kuratieva1,2, S. A. Gromilov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: palladium, rhodium, ethylenediamine, nitrite, double complex salt, single crystal X-ray diffraction study, crystal chemistry


The structure of double complex salts [Pd(NH3)3(NO2)][Rh(NH3)2(NO2)4] and [PdEn2][Rh(NH3)(NO2)5]×0.75H2O is determined by single crystal X-ray diffraction. In the structures, the main structural moieties are identified.