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Journal of Structural Chemistry

2014 year, number 2

CRYSTAL STRUCTURE OF [Co(NH3)5Cl]2(W10O32)В·4Н2O

N. V. Kuratieva1,2, S. P. Khranenko1, S. A. Gromilov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Scientific and Educational Complex В«Nanosystems and Advanced Materials», Novosibirsk, Russia
Keywords: decatungstate, cobalt, complex salt, crystal chemistry, single crystal X-ray diffraction study

Abstract

By single crystal X-ray diffraction the crystal structure of the complex salt [Co(NH3)5Cl]2(W10O32)×4H2O is determined and the IR spectrum is interpreted. The crystal chemical analysis of the structure of complex cations and decatungstate anions and their packing in the structure is performed.