CRYSTAL STRUCTURE OF [Pd3(Ој-OH)(Ој-CH3COO)5]
V. V. Tatarchuk1, A. P. Sergievskaya1, N. V. Kuratieva1,2, I. V. Korol’kov1, L. A. Sheludyakova1, S. A. Gromilov1,2
1A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
2Novosibirsk State University
Keywords: palladium, complex, single crystal X-ray diffraction study, crystal chemistry
Abstract
The crystals of the [Pd3(μ-OH)(μ-CH3COO)5] complex are obtained and characterized using powder and single crystal X-ray diffraction and IR spectroscopy. The crystal structure ( a = 15.6942(6) Å, b = 11.7190(3) Å, c = 9.7871(3) Å, V = 1800.05(10) Å3, space group Pna21, Z = 4) is formed from neutral trinuclear cyclic molecules of [Pd3(μ-OH)(μ-CH3COO)5], in which the OH− group, together with five CH3COO− anions, is a bridge ligand.
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