CRYSTAL STRUCTURE OF A Mn(II) COMPLEX WITH ISATIN-HYDRAZONE-S-BENZYLDITHIOCARBAZATE
J.-J. Xia
Anhui University of Architecture, Hefei, P. R. China
Keywords: X-ray diffraction, dithiocarbazate, isatin, manganese(II) acetate
Abstract
The reaction of Mn(OAc)2·4H2O with isatin-hydrazone-S-benzyldithiocarbazate (HIsa-SBn) results in the formation of a bis-ligand complex [Mn(Isa-SBn)2]·2DMF. Its single crystal is obtained and the structure is determined by X-ray diffraction. It belongs to a monoclinic space group C2/c with the cell parameters: a = 23.290(4) Å, b = 11.4980(18) Å, c = 18.483(5) Å, V = 4087.6(14) Å3. The Mn(II) atom is six-coordinated with two amide O atoms, two azomethine N atoms, and two thiolate S atoms, resulting in a distorted octahedral geometry.
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