COMPLEX STRUCTURE Tri- AND POLYIODIDES OF IODOCYCLIZATION PRODUCTS OF 2-ALLYLTHIOQUINOLINE
E. V. Bartashevich1, I. D. Yushina1, E. A. Vershinina1, P. A. Slepukhin2, D. G. Kim1
1South Ural State University, Chelyabinsk, Russia
2I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
Keywords: triiodides, polyiodides, halocyclization, halogen bond, nonbonding interactions
Abstract
Iodocyclization products of 2-allylthioquinoline are obtained in the form of polyiodides with different stoichiometric compositions. X-ray crystallography data are analyzed for two different crystal structures of 1-iodomethyl-1,2-dihydro[1,3]thiazolo[3,2- а ]quinolinium polyiodides: triiodide C12H11INS+I3¯ and complex polyiodide 2(C12H11INS+I3¯)·I 2. A comparison is made of the nonbonding interactions of dihydrothiazoloquinolinium with atoms of the triiodide anion and complex polyiodide to show the crystal structure features attributed to the participation of molecular iodine.
|
