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Journal of Structural Chemistry

2014 year, number 1

STRUCTURE OF THE MONOCLINIC MODIFICATION OF RE3B

A. P. Tyutyunnik1, T. V. Dyachkova1, Yu. G. Zaynulin1, S. A. Gromilov2,3
1Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg
2A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
3Novosibirsk State University, Novosibirsk
Keywords: rhenium, borides, high pressure, high temperature, X-ray diffraction study, crystal chemistry

Abstract

By powder X-ray diffraction the structure of the monoclinic modification of Re3B is studied. The phase is obtained under high pressure and high temperature (10 GPa, 1800°C) using nanocrystalline rhenium and amorphous boron. The results of the comparative crystal chemical analysis are reported.