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Chemistry for Sustainable Development

2014 year, number 1

Investigation of the Effect of Mixture Composition and Humidity on the Specific Surface Area and Phase Composition of Lithium Оі-Monoaluminate Formed during the Mechanochemical Synthesis from Lithium Carbonate and Aluminium Hydroxide

YA. E. TATARINOVA1,2 and V. P. ISUPOV2
1Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia)
2Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia)
E-mail: isupov@solid.nsc.ru
Keywords: mechanical activation, aluminium hydroxide, lithium carbonate, lithium γ–monoaluminate
Pages: 69–73

Abstract

Lithium γ–monoaluminate was obtained as a result of mechanochemical activation of the mixture of lithium carbonate and aluminium hydroxide in AGO-2 planetary activator, followed by the thermal treatment. The effect of mixture composition and humidity on the phase composition and specific surface of lithium γ–monoaluminate was studied. It was shown that in the variation of the composition and humidity of the mixture the specific surface area of the final product decreases significantly (from 13 to 0.2 m2/g).