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Journal of Structural Chemistry

2013 year, number Приложение 2

SPACE–TIME SCALES IN THE LAGRANGE THEORY OF THERMAL HYDRODYNAMIC FLUCTUATIONS

T. V. Lokotosh1, N. P. Malomuzh1, K. N. Pankratov2
1I. I. Mechnikov Odessa State National University, Ukraine
2Odessa National Polytechnic University, Institute of International Educational Programs, Ukraine
Keywords: Lagrangian particle, Maxwell relaxation time, molecular self-diffusion coefficient

Abstract

The value and temperature dependence of the Maxwell relaxation time of viscous tensions and the Lagrangian particle radius, which are the main space-time scales in the Lagrange theory of thermal hydrodynamic fluctuations, are discussed. These parameters play the key role in the estimations of the relative value of the collective component of the molecular self-diffusion coefficient. Special attention is paid to the consistency of estimates obtained by different methods.