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Journal of Structural Chemistry

2013 year, number 5

CRYSTAL STRUCTURE OF SALTS OF THE trans-[Rh(NH3)2(NO2)4]– ANION WITH K+, Cs+, Ag+, AND (CH3)4N+ CATIONS

A. V. Belyaev, A. I. Smolentsev, I. A. Baidina, S. V. Tkachev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk
Keywords: rhodium, trans-diamminetetranitrites, salts, crystal structure, 14,15N NMR

Abstract

Complex rhodium(III) salts with the composition trans-М[Rh(NH3)2(NO2)4], where М = K+, Cs+, Ag+, and N(CH3)4+, are prepared and characterized. The molecular and crystal structures are determined by X-ray crystallography.