INTERPENETRATING FRAMEWORKS IN THE STRUCTURE OF THE [(SnMe3)3Re6Se8(CN)6] CLUSTER COMPLEX
A. Yu. Ledneva, A. V. Virovets, N. G. Naumov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
Keywords: rhenium, octahedral cluster, tin
Abstract
Single-crystal X-ray diffraction is used to determine the structure of a new compound based on an octahedral cyanide anionic cluster complex of rhenium and a trimethyltin(IV) cation: {(SnMe3)3[Re6Se8(CN)6]} (1). The crystallographic characteristics: space group С2/с, a = 13.9898(14) Å, b =15.334(2) Å, c = 20.761(2) Å, β = 97.75(0)°, V = 4412.91(90) Å3, Z = 4, dx = 3.607 g/cm3, and R = 0.0526. The compound has a framework structure; two porous frameworks with pcu topology interpenetrate each other.
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