INFLUENCE OF THE OUTER-SPHERE CATION NATURE ON THE CRYSTAL STRUCTURES OF SALTS WITH A CIS-[Rh(NH3)2(NO2)4]– ANION
I. A. Baidina, A. V. Belyaev, I. V. Korol’kov, S. N. Vorobieva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
Keywords: rhodium, cis-diammine tetranitrites, salts, crystal structure
Abstract
Complex rhodium(III) salts of the composition cis-M[Rh(NH3)2(NO2)4]×n H2O, where M = K+, Cs+, Ag+, (CH3)4N+, are synthesized and described. Their molecular and crystal structures are determined by single crystal X‑ray diffraction.
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