BINUCLEAR CLUSTER COMPLEXES OF MOLYBDENUM CONTAINING 2,2'‑BIPYRIDINE AND 1,10-PHENANTHROLINE: SYNTHESIS AND STRUCTURE
A. L. Gushchin1,2, Yu. L. Laricheva1, N. I. Alferova1, A. V. Virovets1, M. N. Sokolov1,2
1A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
2Novosibirsk State University
Keywords: binuclear clusters, molybdenum, polypyridine ligands, crystal structure, IR spectra
Abstract
By the interaction between (Et4N)2[Mo2O2S8] and I2 in DMF with a subsequent addition of 2,2'-bipyridine or 1,10-phenanthroline, new binuclear complexes [Mo2O2S2I 2(bipy)2] (1) and [Mo2O2S2I2(phen)2] (2) are obtained. The structure of [Mo2O2S2I2(bipy)2] is determined using single crystal X‑ray diffraction. The compounds are characterized by elemental analysis and IR spectra. The [MoO(S2)2(bipy)] complex as a product of oxidative destruction of 1 is isolated and characterized.
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