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Journal of Structural Chemistry

2013 year, number 4

EFFECT of violations of the structure and layer packing on the diffraction pattern of gibbsite and bayerite

K. I. Shefer1, S. V. Cherepanova1,2, S. V. Tsybulya1,2, V. P. Isupov3, Г€. M. Moroz1
1G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
2Novosibirsk National Research State University
3Institute of Solid State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
Keywords: gibbsite, bayerite, aluminum hydroxides, intercalation, structure, defects, packing defects, simulation of diffraction patterns

Abstract

Using the simulation method for the diffraction patterns of one-dimensionally disordered materials, the effect of different violations in the layered structure of aluminum trihydroxides (gibbsite and bayerite) on their diffraction patterns is analyzed. The features of the diffraction patterns of a disordered gibbsite sample obtained by intercalation–deintercalation of lithium salts are considered.