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Journal of Structural Chemistry

2013 year, number 2

MOLECULAR STRUCTURE 5-[(TRIPHENYLPHOSPHORANYLIDENE)HYDRAZONO]- EXO-3-AZATRICYCLO[5.2.1.02.6]DECANE-4-ONE

Yu. R. Galina1, A. N. Lobov1, R. M. Sultanova1, L. V. Spirikhin1, V. A. Dokichev1, K. Yu. Suponitsky2
1Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa
dokichev@anrb.ru
2A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow
Keywords: 5-diazo-exo-3-azatricyclo[5.2.1.0 2,6]decane-4-one, phosphazines, molecular structure, single crystal X‑ray diffraction study

Abstract

The molecular structure of 5-[(triphenylphosphoranylidene)hydrazono]-exo-3-azatricyclo[5.2.1.02.6]decane-4-one is determined. The C27H26N3OP compound crystallizes in the space group P-1: a = 9.2163(9) Å, b = 11.1102(11) Å, c = 11.9397(12) Å, α = 74.284(2)°, β = 78.532(2)°, γ = 72.004(2)°.