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Journal of Structural Chemistry

2012 year, number 6

CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO(BENZOYLOXYMETHYL)TRIFLUOROSILANE AT 120 K

É. A. Zel’bst, A. A. Korlyukov, M. G. Voronkov
Keywords: molecular structure, X‑ray diffraction study, draconoids, (aroyloxymethyl)trifluorosilanes

Abstract

The crystal and molecular structure of 4-chloro(benzoyloxymethyl)trifluorosilane 4-ClC6H4COOCH2SiF3 was redetermined using X‑ray diffraction. The coordination polyhedron of the silicon atom in this structure is a trigonal bipyramid. The length of the axial O → Si coordination bond is 2.074(1) Å.