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Journal of Structural Chemistry

2012 year, number 6

PHOTOELECTRON SPECTRA OF POWDER AND SINGLE CRYSTALLINE CHROMIUM-COPPER DISULFIDES

E. V. Korotaev, N. N. Peregudova, L. N. Mazalov, V. V. Sokolov, A. V. Kalinkin, N. A. Kryuchkova, Yu. P. Dikov, M. I. Buleev, I. Yu. Filatova, A. Yu. Pichugin
Keywords: layered chromium-copper disulfide, transition metal dichalcogenides, magnetic semiconductors, solid electrolytes, photoelectron spectroscopy

Abstract

2p3/2,1/2 Photoelectron spectra of single crystalline specimens of chromium-copper disulfides CuCrS2 and CuCr0.85V0.15S2 are studied. It is shown that the spectra of single crystalline specimens substantially differ from the corresponding spectra of chromium-copper disulfides in the powder state.