CRYSTAL AND MOLECULAR STRUCTURE OF THE [Zn(HL)Cl]Г—EtOH COMPOUND, (Н
2L = CHIRAL
bis(MENTHANE)PROPYLENEDIAMINODIOXIME)
L. A. Glinskaya, Z. A. Savel’eva, S. N. Bizyaev, A. V. Tkachev, S. V. Larionov
Keywords: complex, solvate, zinc(II), bis(menthane) propylenediaminodioxime, structure
Abstract
The crystal structure of a solvate [Zn(НL)Cl]×EtOH is determined by single crystal X-ray crystallography (150 K, Bruker X8 Apex CCD autodiffractometer, МоKa radiation). The crystals are triclinic, unit cell parameters are: a = 7.4755(4) Å, b = 13.9701(11) Å, c = 14.4593(19) Å, α = 82.277(2)°, β = 75.410(2)°, γ = 75.356(1)°, space group Р1. The structure of the solvate contains two crystallographically independent complex [Zn(НL)Cl] molecules and two non-coordinated ethanol molecules. In each of the molecules, Zn2+ ions coordinate N atoms of tetradentate chelating ligands НL– and a Cl atom. ClN4 polyhedra have a distorted tetragonal pyramidal geometry. EtOH molecules make H-bonds with the complex molecules, thus facilitating the formation of chains along the х axis.
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