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Avtometriya

2009 year, number 3

4361.
Status and Prospects of Micro- and Nanoelectromechanics

E. G. Kostsov
Keywords: microelectromechanics, MEMS, electromechanical conversion of energy, microelectronics, microoptics, optoelectromechanics, adaptive optics, frequency generator, accelerometer, gyroscope, microactuator, nanoelectromechanics, RF commutator, RF filter, pressu
Pages: 3-52

Abstract >>
Micro-electro-mechanical systems (MEMS) are devices that display the most intense development in modern microelectronics. At the moment, however, the majority of electronic engineers and users of hi-tech devices do not possess sufficient general information about this new direction in microelectronics. The present paper describes the current status of this direction, numerous possible applications, and prospects of its further development, including the transition to the nanometer range and creation of nanoelectronic elements. Specific features of operation of some particular MEMS devices, their characteristics, and areas and scales of applications are considered.



4362.
Multichannel Linear Detector for x -ray Spectroscopy

V. A. Labusov, L. N. Mazalov, S. V. Fomenko, D. O. Selyunin, A. V. Bekhterev
Keywords: x-ray spectroscopy, emission spectra, absorption spectra, linear x-ray detector, photodiode array
Pages: 53-61

Abstract >>
This paper considers a new linear multichannel x-ray detector designed on the basis of a BLPP-369M4 silicon photodiode array (2612 photodiodes, array pitch 12.5 μm, height 4 mm, and dynamic range 104). The structure and characteristics of the multichannel detector are given, along with the Kα1,2, Kβ1, andKβ5 x-ray emission lines and a K-edge absorption spectrum of metallic copper recorded on a universal URS-2I spectrometer using this detector. The resolution and the signal/noise ratio of these spectra are superior to those of spectra recorded by an SRPP-21 gas ionization counter at the same recording time. The detector has a spatial resolution of 20 μm and an x-ray detection limit to equal 1 quantum at λ = 1.54 Å. It is suitable for studying the fine structure of absorption spectra at 1-10 Å.



4363.
Specific Features of Operation of Electrostatic Microgenerators of Energy

V. P. Dragunov, E. G. Kostsov
Keywords: microelectromechanics, electrostatics, microgenerator of energy, microvibration
Pages: 62-73

Abstract >>
Specific features of operation of one- and two-capacitor microelectromechanical converters (MEMC) of energy of mechanical microscopic vibrations into electric energy with a modulated electrode-gap magnitude and with allowance for the mutual influence of electrical and elastic forces are analyzed, and the characteristics of these two devices are compared. The main factors restricting the increase in MEMC power are demonstrated to be the effects of "collapsing" and the condition of conservation of positive rigidity of the system. Expressions for estimating the limiting MEMC parameters are derived. The possibility of electrical energy generation in the presence of "real" sources of wide-spectrum microscopic vibrations is considered.



4364.
Optimal Estimation of the Position of Non-Gaussian Impulse Noise in Images

E. A. Samoilin
Keywords: pulse noise, optimal estimation, spatial position, image filtering, average risk
Pages: 74-82

Abstract >>
An algorithm for optimal estimation (in the sense of the minimum average risk criterion) of the spatial position of non-Gaussian impulse noise in digital images is proposed based on the signal difference between the center of the slide aperture and its other elements. An expression for the boundary values of the admissible signal interval is obtained that provides the potentially achievable zero probability of noise estimation error. Results of numerical studies of the efficiency of the synthesized algorithm show its advantages over the well-known nonoptimal algorithm.



4365.
Frequency Search Algorithm for Estimating Polyharmonic Signal Model Parameters

V. G. Getmanov
Keywords: polyharmonic models, estimation, parameters, nonstationary multifrequency signals
Pages: 83-89

Abstract >>
A frequency search algorithm for estimating polyharmonic signal model parameters is considered. The algorithm uses the symmetry property of functionals of residual partial sums. The proposed frequency search algorithm provides a decrease in the amount of calculation. The efficiency of solving the estimation problem is determined.



4366.
Method of Directed Enumeration of Alternatives in the Problem of Automatic Recognition of Half-Tone Images

A. V. Savchenko
Keywords: automatic image recognition, image recognition, learning recognition, minimum information discrimination criterion.
Pages: 90-98

Abstract >>
The problem of automatic recognition of half-tone images based on the minimum information discrimination principle is formulated and solved. A method of directed enumeration of the set of alternatives in the Kullback-Leibler information metric is proposed as opposed to the method of complete enumeration of competing hypotheses. A program and results of an experimental study of the method are presented. It is shown that the proposed algorithm is characterized by increased accuracy and reliability of automatic image recognition.



4367.
Group of Nonlinear Spheroidal Perspectives

A. M. Kovalev
Keywords: display of visual scenes, space compression, spheroid, nonlinear perspectives
Pages: 99-106

Abstract >>
A group of nonlinear perspectives for displaying three-dimensional visual scenes on elliptic surfaces and the interior of spheroids is considered. Scenes are transformed using a patented method for displaying objects with space compression and subsequent projection onto a sphere.



4368.
One Method for Restoration of Blurred Images

V. R. Fazylov, N. K. Shcherbakova
Keywords: statistical regularization, restoration of blurred images, multistep support vector method
Pages: 107-110

Abstract >>
A new method is proposed to reduce image distortions caused by random noise and rectilinear uniform motion of the object or recording system. The of a restoration model is based on a statistical regularization method, and the obtained system of linear equations and inequalities is solved using a multistep support vector method. An advantage of this approach is that the iterative nature of the algorithm makes it possible to take into account the a priori information on the solution represented by the inequalities. The results of numerical experiments showing the efficiency of the algorithm are given.



4369.
Estimating the Efficiency of Digital Filtering of Periodic and Impulse Noise Based on Local Statistics

V. G. Galalu, V. V. Sarychev, M. M. Klopot
Keywords: impulse noise, suppression ratio, smoothing, digital filter, modeling, impulse noise cancellation algorithm
Pages: 111-116

Abstract >>
This paper presents the results of modeling of several digital filtering algorithms of the ADC output codes for suppressing periodic and impulse noise signals and normal noise. The algorithms were tested in LabVIEW. It was shown that they provided real-time suppression of normal and impulse noise to a level from 57 to 63 dB.



4370.
Identification of Subsurface Objects by Amplitude-Frequency Response Characteristics in the Microwave Range

V. P. Lubov, V. M. Gruznov
Keywords: microwave range, balanced antenna detectors, spectra of reflected signals
Pages: 117-122

Abstract >>
The resonant properties of dielectric subsurface objects in the microwave range are considered. The paper gives formulas and experimental results for the properties of some small-size (∅ 200 mm) dielectric objects in sand with a moisture content of 6% at depths up to 8 cm at frequencies of 270-620 MHz and for metal springs which can be part of these objects at frequencies of 900-1200 MHz. It is shown that the objects can be identified by their amplitude-frequency characteristics in the microwave range.



4371.
Efficient Estimation of Generator Instability Characteristics in the Time Domain

B. D. Borisov
Keywords: efficient estimation, frequency instability characteristic, Allan variance, flicker noise, variance minimum, optimal filtering
Pages: 123-126

Abstract >>
This paper considers the problem of determining the true (nonsampling) variance of the Allan parameter-the main frequency instability characteristic of frequency generators, synthesizer, and standards in the time domain. The variables influencing the efficiency of estimating the parameter are determined and compared in magnitude. For frequency fluctuations with flicker noise power-law power spectral density, the parameter estimate accuracy is most significantly affected by the variance of the estimated average frequency-the quantity included in the Allan parameter and defining the quality of averaging over a finite time interval.



"Philosophy of Education"

2009 year, number 2

4372.
INTERACTION OF EDUCATION AND SCIENCE AS INTEGRAL SOCIAL PHENOMENA: CURRENT VIEWS

N. A. Knyazev, O. I. Korolchuk
Keywords: quality of higher education, education and science as integral social phenomena, post-industrial society, qualitization of modern society, concepts of quality, quantity, measure
Pages: 5-12

Abstract >>
The article determines and describes the main stages of the theoretical analysis on the «quality of higher education» concept. The philosophical and methodological principles of application of the «quality» concept are introduced. It is shown that these principles are applicable to provide conceptual strategies in the higher education system development in the post-industrial society.



4373.
ABOUT SPECIFICITY OF MODERN INTEGRATION EDUCATION AND SCIENCE

E. A. Pushkareva
Keywords: integration of education and a science, a scientific component of education, crisis of educational-scientific sphere
Pages: 12-17

Abstract >>
In clause specificity of modern integration processes in a domestic science and education is analyzed. The urgency of a problem is connected with search of ways of an output of a science and education from the crisis situation shown in inadequacy of development by a theoretical-methodological scientific component of modern domestic education. The author brings to a focus that specificity of integration of education and a science directly is connected with character of that historical epoch in which there is a education and development of this process, and also directly is connected with historical traditions (including regional), setting an orientation and actually specificity of development and education, and a science.



4374.
ABOUT MODERN SPECIFICITY OF DEVELOPMENT DOMESTIC EDUCATION

A. V. Nalivaiko, V. I. Panarin
Keywords: methodological and world outlook functions of philosophy, philosophy of education, globalization, аксиология, праксиология, ontology
Pages: 17-24

Abstract >>
The problem of development of domestic formation in conditions of globalization is based on a necessary philosophical reflection, and should be considered in a context of questions of social philosophy, in a context of questions of specificity of modern development of Russia which cause development of modern domestic formation. There is a deep interrelation of philosophy of formation with political, strategic, tactical doctrines of educational activity. The radical changes which have been last in a public life of Russia, have caused to a turn of transformations in sphere of formation. In clause it is shown, how being the factor of reflection social dynamics of life, formation, as well as all society, experiences deep system crisis, there is an active search of ways of an output from this crisis.



4375.
MODERN SPECIFICITY OF PHILOSOPHICAL JUDGEMENT OF PROBLEMS OF MODERN EDUCATION

M. S. Begalinova
Keywords: philosophy of education, educational processes, cultural paradigms of education
Pages: 24-31

Abstract >>
In clause education as cultural phenomenon and the major party of ability to live of a society is analyzed. A basis of the methodological analysis of educational processes is the philosophy of education. The main task of modern philosophy of education becomes judgement of the base bases of education and a pedagogical science, development of an ideal of the formed person, finding-out of a place of education in modern culture. The basic function of philosophy of education consists in development of ways and ways of the sanction of the arisen crisis of education, and also in creation of an image of new school. In opinion of the author, philosophy of education as the independent scientific discipline can offer a fundamental substantiation of an ideal of erudition and the purposes of modern education.



4376.
PROBLEMS OF PREVENTION OF LEGAL NIHILISM IN THE SYSTEM OF EDUCATION

E. N. Mikhailova
Keywords: state, education, communication, law, legal nihilism, morality, social consciousness, sense of justice, values
Pages: 31-36

Abstract >>
In the article, such aspect of the deformity of social consciousness as legal nihilism is under analysis, as well as the role of education in the correction of this process. A special attention is given to the problem of estimation of the law from the positions of morality as one crucial source of the Russian legal nihilism. The author proves the impossibility of the estimation of state and law from moral positions. Social order is designated as the limiting positive pole of law.



4377.
THE PROBLEM OF DEFINING THE NOTION OF LEGAL ENTITY IN TEACHING OF LAW

T. V. Melnikova
Keywords: legal entity, cosmic model of the world, universal model of the world
Pages: 36-42

Abstract >>
The article is devoted to the research of legal entity as a social relation. The aim is to show the necessity of teaching the law according to the traditions of society. The author studies legal entity according to the cosmic model of the world.  The result of research is that the person including legal entity is a social relation, which is determined by the actual law and other social rules which are completed by the law.



4378.
INNOVATIVE TECHNOLOGIES AND THE PROBLEM OF SUCCESS OF THE PROSPECTIVE SPECIALIST

a:2:{s:4:"TYPE";s:4:"TEXT";s:4:"TEXT";s:34:"Е. Т. Konyukhova, Т. V. Konyukhova";}
Keywords: model of mindset formation, competence, success mindset - individual and personal value, innovative technologies
Pages: 42-46

Abstract >>
The importance of the problem of the success mindset can be derived from the necessity of creating in the educational space of the higher education institution an integral complex of conditions, which foster professional formation of the prospective specialist and his/her success in the professional activity. The competence orientation in the educational space of the specialist training gives rise to the problem of revealing the "field" of success of the person in the social and work activities. There are considered some questions concerning modern perusal of the «success of the person» context and the introduction of innovative technologies of training of the successful specialist. The offered model provides formation of the success mindset as a competence and personal value of the prospective specialist.



4379.
DESIGN-TECHNOLOGICAL THINKING AS A TOOL OF SPECIALIST'S SOCIAL ADAPTATION

V. I. Ivashchenko
Keywords: pedagogical system, drawing and geometrical training, design-technological thinking, personality, social adaptation
Pages: 46-52

Abstract >>
a:2:{s:4:"TYPE";s:4:"TEXT";s:4:"TEXT";s:789:"This paper describes the results of investigation of the design-technological mentality formation in a process of graphic disciplines studies and how the mental level of the design-technological thinking influences the social-personal potential of the mechanical engineer. The research was carried out within the framework of the departmental analytical special-purpose program "Development of the higher education scientific potential (2006-2008)"; project RPN 3.1.1.11077 "Development of teaching materials and educational technology for training high level engineers for innovation activity in scientifically based high-technological machine building industry". The proposed principles have been realized at the «Aircraft engines» Department of Samara State Aerospace University (SSAU).";}



4380.
PHILOSOPHICAL FOUNDATIONS OF THE MODERN EDUCATIONAL TECHNOLOGY

R. N. Shmatkov
Keywords: philosophical foundations, social philosophy, educational technology, system-active approach, emotional perception, creative approach
Pages: 52-58

Abstract >>
The aim of this article is to describe philosophical foundations of modern educational technology with application of mathematical methods and informational technologies. This educational technology was developed by the author with the aim of quality increasing for higher law education in our country. Modern problems of the domestic law education are touched upon in the article. It is necessary to get over these problems to realize the effective training of highly qualified and highly-moral specialists in the branch of jurisprudence. Highly-moral and well educated jurists are necessary for our country to realize democratization of all public life spheres. Therefore, educational quality of specialists in the branch of jurisprudence in this time is a problem of the State importance.



4381.
INFLUENCE OF SOCIAL COOPERATION ON THE COLLECTIVE LABOR RESULTS

T. A. Vaneeva
Keywords: social cooperation, social effect, cinergy action results
Pages: 58-64

Abstract >>
The subject of the author's analysis is connected with a unique experiment in the sphere of higher education in Novosibirsk from the year 2006 till present time.  The main aim of this experiment is student's participation in a new administrative project of teaching the management personnel through solving practical problems. The unity of the student's theory and practice has showed high social results in different aspects of our life. Young people want to see our country as a powerful motherland.



4382.
EDUCATION OR PROGRAMMISATION?

V. A. Kutyrev
Keywords: education, humanism, technology, values, informatization, culture, programming, pluralism, ecology
Pages: 64-70

Abstract >>
The subject under analysis is the change in relation between functional and value-related components of contemporary education system. Domination of functionalism is reflected by its unlimited informatization, which results in its turning into programming and, finally, gets automated.  If we want to keep a humanistic character of our education we need to reproduce in it all forms of culture, not just the scientific ones. The School must be a place of life.  We need a kind of ecology of education system.



2009 year, number 2

4383.
PHASE FORMATION IN THE SYSTEM (Z = 1.00). CRYSTAL STRUCTURE AND PROPERTIES OF SODIUM HETEROPOLYHEXATUNSTEN NICKELATE(2+)Na4[Ni(OH)6W6O18]·16H2O

a:2:{s:4:"TEXT";s:74:"G. M. Rozantsev, S. V. Radio, N. I. Gumerova, V. N. Baumer, О. В. Shishkin";s:4:"TYPE";s:4:"text";}
Keywords: heteropoly compound, tungstate, sodium heteropolyhexatungsten nickelate (2+), Anderson-Evans structure, crystal structure, IR spectroscopy, X-ray diffraction analysis, thermal analysis
Pages: 311-319

Abstract >>
The green crystals of Ni1.5H[Ni(OH)6W6O18]·12.5H2O and blue crystals of Na4[Ni(OH)6W6O18]·16H2O were isolated from the acidified (to Z = ν(H+)/ν = 1.00) solutions of Ni(NO3)2-Na2WO4-HNO3-H2O systems. The synthesized salts were identified by chemical analysis, XRPA, and IR spectroscopy. It was shown that the heteropolyanions belonged to the Anderson-Evans type of structure. An X-ray diffraction study of Na4[Ni(OH)6W6O18]·16H2O was carried out (Mr = 1932.07, triclinic, space group P-1, a = 8.0089(11) Å, b = 10.5758(14) Å, c = 12.1987(16) Å; α = 69.268(13)°, β = 71.069(12)°, γ = 83.816(11)°; V = 914.0(2) Å3 at T = 293 K, Z = 1, ρcal = 3.510 g/cm3, F000 = 874, μ = 19.470 mm-1,
-16 ≤ h ≤ 16, -21 ≤ k ≤ 21, -24 ≤ l ≤ 24; the final R factors are RF = 0.0277, wR2 = 0.0469 for the observed reflections (RF = 0.0606, wR2 = 0.0523 for all independent reflections); S = 0.953; CSD-419883). The structure was solved by direct methods and refined in an anisotropic approximation. Hydrogen atoms were found in a difference synthesis and refined in an isotropic approximation with geometrical limitations. The nature of water in Na4[Ni(OH)6W6O18]·16H2O was characterized by DTA. XRPA was used to identify the thermolysis products of heteropoly compounds.



4384.
STUDY OF THE Re0.50Rh0.50 PRODUCTS OF THERMOBARIC TREATMENT

S. A. Gromilov, T. V. D'yachkova, K. V. Yusenko, I. B. Kireenko, A. P. Tyutyunnik, Y. G. Zainulin
Keywords: rhodium, rhenium, solid substitution solution, high pressure, high temperature, X-ray phase analysis, thermolysis, microhardness
Pages: 320-324

Abstract >>
The products of thermobaric treatment of the metastable Re0.50Rh0.50 nanocrystalline phase (а = 2.733(2) Å, с = 4.364(4) Å, space group P63/mmc, CSR ~5 nm) in a high-pressure chamber were studied. Storage of the phase at 2000°С and 1.5 GPa for 3 min led to the formation of a fused particle (∅~1 mm). The initial composition did not change, but the coherent scattering region (CSR) increased to 52 nm. An increase to 4 GPa in pressure also did not lead to a decomposition of the metastable Re0.50Rh0.50 phase, the unit cell parameters remained the same, and the size of the CSR increased by a factor of four.



4385.
CRYSTAL-CHEMICAL ANALYSIS OF THE STRUCTURES OF MINERALS WITH [Hg2]2+ DUMBBELLS

S. V. Borisov, S. A. Magarill, N. V. Pervukhina
Keywords: atomic sublattices, crystal structures of [Hg2]2+-containing minerals, structure-forming factors
Pages: 325-334

Abstract >>
An analysis of the structures of minerals with [Hg2]2+ dumbbells including poyarkovite [Hg2]3Cl2O2, shakhovite [Hg2]2Sb(OH)3O3, vasilyevite Hg20O6I3Br2Cl(CO3), and kelyanite [Hg2]6[SbO6]BrCl2 was carried out. The determining factor in structure formation is the ordering of the centers of the cluster groups of mercury and large anions by systems of equidistant parallel planes with dhkl ~ 2.5-4.5 Å. The different combinations of atoms and fragments in the structure are ordered by their own pseudotranslation lattices; this probably reflects the stages of crystallization. The crystal structures under study are examples of balance between the local interatomic interactions and the forces that create long-range order for different stoichiometries, masses, and sizes of components.



4386.
CRYSTAL STRUCTURE AND LUMINESCENCE OF ANTIMONY(III) BROMIDE WITH ANILINE

B. V. Bukvetskii, T. V. Sedakova, A. G. Mirochnik
Keywords: crystal structure, antimony(III), aniline, luminescence
Pages: 335-340

Abstract >>
The atomic structure of antimony(III) bromide crystals with anilinium was determined by X-ray diffraction analysis of (С6H5NH3)2SbBr5 (a = 19.704(3) Å, b = 7.914(1) Å, c = 25.556(4) Å; space group Pbca, Z = 8, ρcalc = 2.365 g/cm3). The crystal structure consists of infinite chains of [SbBr5]2- complex anions formed by sharing six vertices and the anilinium (С6H5NH3)+ cations, through which the chains are linked in layers by N-H…Br hydrogen bonds. The geometrical aspects that determine the luminescent spectral properties of the complex are discussed.



4387.
TRANS-DINITRO- AND TRANS-DINITRATORUTHENIUM COMPLEXES [RuNO(NH3)2(NO2)2(OH)] AND [RuNO(NH3)2(H2O)(NO3)2]NO3·H2O

M. A. Il'in, E. V. Kabin, V. A. Emel'yanov, I. A. Baidina, V. A. Vorob'yov
Keywords: ruthenium, nitroso complexes, ammino complexes, nitro complexes, nitrato complexes, spent nuclear fuel, X-ray analysis
Pages: 341-348

Abstract >>
Methods for the synthesis of trans-diammino complexes [RuNO(NH3)2(NO2)2(OH)] (I) and [RuNO(NH3)2(H2O)(NO3)2](NO3)·H2O (II) are suggested. The compounds were studied by IR spectroscopy and X-ray phase and X-ray structural analyses. Crystal data: space group P-1; a = 6.2328(2) Å, b = 11.0488(3) Å, c = 11.0981(4) Å; α = 71.942(1)°, β = 83.291(1)°, γ = 86.877(1)° (I); space group P21; a = 6.6290(2) Å, b = 13.4389(5) Å, c = 7.0180(2) Å, β = 114.281(1)° (II). Complex II readily lost some part of crystal water on storage in open air.



4388.
STRUCTURE AND THERMAL PROPERTIES OF [RhPy4CL2]X COMPLEX SALTS (X = CL-, ReO, ClO)

D. B. Vasilchenko, I. A. Baidina, E. Y. Filatov, S. V. Korenev
Keywords: rhodium, pyridine, perrhenate ion, perchlorate ion, X-ray analysis, thermal analysis
Pages: 349-356

Abstract >>
[RhPy4Cl2]Cl·4H2O (I), [RhPy4Cl2]ReO4 (II), [RhPy4Cl2]ClO4 (III), and [RhPy4Cl2]ReO4·2H2O complex salts were synthesized. The crystal structure of compounds II (P4/ncc, a = 25.5655(3) Å, c = 14.3521(4) Å), III (P21/n, a = 13.5308(3) Å, b = 15.1044(5) Å, c = 23.3457(8) Å, β = 93.327°), and dyhydrate of II (Pbcm, a = 10.6199(9) Å, b = 10.4964(9) Å, c = 22.9834(16)Å) was determined by X-ray diffraction analysis. The thermal transformations of the complexes were studied by differential thermal analysis. The substances were characterized by IR spectroscopy, XRPA, and element analysis



4389.
DETERMINATION OF HYDROGEN ATOM POSITIONS IN BASIC LEAD CARBONATE HYDROCERUSSITE BY QUANTUM CHEMICAL METHODS AND SIMULATION OF THE VIBRATIONAL SPECTRA

M. R. Bissengaliyeva
Keywords: atomic positions, crystal structure, vibrational spectra, thermodynamic functions, quantum chemical calculation
Pages: 357-361

Abstract >>
Positions of hydrogen atoms in the crystal structure of basic lead carbonate hydrocerussite are determined by the РМ5 quantum chemical method. Raman and infrared spectra as well as thermodynamic functions are calculated for this compound by the theory of crystal lattice dynamics.



4390.
MOLECULAR STRUCTURE OF PARAMAGNETIC BIS-DIISOBUTYL DITHIOPHOSPHINATE COMPLEXES OF LANTHANIDES(III) WITH 1,10-PHENANTHROLINE IN SOLUTION BY THE DATA OF NMR RELAXATION SPECTROSCOPY

S. P. Babailov, V. L. Varand
Keywords: lanthanide-induced shifts, lanthanides, paramagnetic complexes of lanthanides, paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates, nuclear magnetic resonance (NMR), NMR relaxation spectroscopy, molecular structure, luminescent se
Pages: 362-364

Abstract >>
NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.



4391.
MÖSSBAUER SPECTRA OF IRON DOPED CuCrS2

V. A. Varnek, V. V. Sokolov, I. Y. Filatova, S. A. And
Keywords: sulfides, iron, M?ssbauer spectra, phase composition, structure
Pages: 365-368

Abstract >>
Mössbauer spectroscopy is used to study the state of iron atoms in samples with a composition of
CuCr1-xFexS2 (x = 0.01-0.30). It is shown that at x ≤ 0.02 samples are solid solutions in which iron atoms have an oxidation number of 3+ and replace chromium atoms in octahedral sites. When the iron concentration increases, the second phase - chalcopyrite CuFeS2 - forms along with the solid solution. The relative iron concentration in this phase increases from 11% at x = 0.03 to 52% at x = 0.30.



4392.
INTERRUPTED SUPER FRAMEWORK OF THE CRYSTAL STRUCTURE OF Cs[Be2(PO4)(PO4H)] CESIUM DIBERYLLIUM PHOSPHATE HYDROPHOSPHATE

V. V. Bakakin, Y. V. Seretkin, S. P. Demin
Keywords: crystal structure, cesium beryllium phosphate, para framework, super framework
Pages: 369-373

Abstract >>
The crystal structure of cesium diberyllium phosphate hydrophosphate Cs[Be2(PO4)(PO4H)] obtained hydrothermally is analyzed. Unit cell parameters are: a = 4.8860(5) Å, b = 10.7330(11) Å, c =
13.0061(15) Å, α = 92.540(10)°, β = 92.451(9)°, γ = 90.948(9)°, space group P 1. In the structural motif consisting of РО4 and ВеО4 tetrahedra, Ве,Р two-link chains and ribbons are distinguished, typical of a short a-translation of ≈4.9 Å. The presence of ternary and terminal O ligands along with bridging ones determines the term interrupted super framework. The group of two Ве tetrahedra with a common edge is detected for beryllium phosphates for the first time.



4393.
CRYSTAL STRUCTURE OF A NEW POLYMORPHIC MODIFICATION OF β-K2[Pd(NO3)4]

S. P. Khranenko, I. A. Baidina, S. A. Gromilov
Keywords: palladium, nitrates, coordination compounds, crystal structure, crystal chemistry
Pages: 374-377

Abstract >>
X-ray diffraction is applied to study a new crystalline modification of K2[Pd(NO3)4]-β-K2[Pd(NO3)4]. It is found that the phase is isostructural with Na2[Pd(NO3)4] and Rb2[Pd(NO3)4]. Square coordination of the Pd atom is formed by oxygen atoms of monodentately coordinated nitrate groups.



4394.
CRYSTAL STRUCTURE OF THE BIOCTAHEDRAL CLUSTER COMPLEX K6[Re12Cs17(CN)6]·2CH3OH·10H2O

Y. V. Mironov, S.-J. Kim, V. E. Fedorov
Keywords: rhenium, bioctahedral thiocyanate cluster, synthesis, crystal structure
Pages: 378-380

Abstract >>
The cluster complex of K6[Re12CS17(CN)6]·2CH3OH·10H2O composition is separated by recrystallization of the K6[Re12CS17(CN)6]·20H2O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) Å, c = 14.631(4) Å, V = 1531.3(5) Å3, Z = 1, and dcalc = 3.720 g/cm3.



4395.
CRYSTAL STRUCTURE OF [Mn(1,10-C12H8N2)3](B6H7)2

T. M. Polyanskaya, M. K. Drozdova, V. V. Volkov, K. G. Myakishev
Keywords: [tris-phenanthroline manganese(II)](2+) cation, heptahydro-closo-hexaborate(1-) anion, single crystal X-ray diffraction analysis
Pages: 381-385

Abstract >>
A new compound is synthesized; its crystal structure is studied by XRD at 100 K. Crystallographic data: C36H38B12N6Mn, M = 739.39, triclinic symmetry, space group unit cell parameters: a = 10.3131(3) Å, b = 13.4839(4) Å, c = 15.1132(4) Å; α = 97.696(1)°, β = 108.324(1)°, γ =
102.211(1)°; V = 1903.9(1) Å3, Z = 2, dcalc = 1.290 g/cm3. The structure is solved by direct and Fourier methods and refined by full-matrix LSM in the anisotropic (isotropic for hydrogen atoms) approximation to the final factor R1 = 0.036 for 10169 Ihkl ≥ 2σI (Bruker-Nonius X8 APEX CCD diffractometer, λMoKα). The structure contains two crystallographically different anions.



4396.
CRYSTAL STRUCTURE OF A TWO-DIMENSIONAL CO(II) COORDINATION POLYMER: [Co(μ-PP)2(SCN)2]n [PP = 2-(PYRIDINE-3-YLOXY)PYRAZINE]

H. Li, H.-Y. Zhao, S.-G. Zhang, J.-M. Shi
Keywords: crystal structure, cobalt(II) complex, 2D polymer, layered structure
Pages: 386-390

Abstract >>
Solvothermal reaction (water/methanol) of cobalt perchlorate hexahydrate, sodium thiocyanate and 2-(pyridine-3-yloxy)pyrazine (PP) resulted in the formation of a two-dimensional coordination polymer [Co(μ-PP)2(SCN)2]n. The solid complex has been characterized by elemental analysis and IR spectroscopy; its crystal structure was determined by X-ray crystallography. The complex crystallizes in the monoclinic system, space group P21/n, a = 7.4643(19), b = 9.237(2), c = 15.540(4) Å, β = 94.995(5)°, V = 1067.4(5) Å3, Z = 1. In the crystal structure each 2-(pyridine-3-yloxy)pyrazine molecule acts as a bidentate bridging ligand coordinating to two adjacent Co(II) ions with Co…Co separation of 9.5176(18) Å to yield a two-dimensional sheet structure in the plane (-1 0 1).



4397.
MOLECULAR AND CRYSTAL STRUCTURE OF A NEW COMPOUND METHYL-18R-13-ISOPROPYL-10A,7-DIMETHYL-4-OXO-1-OXAHEXACYCLO×[12.4.0.05А,4A.013,1201,1A.010A,6А]HENEICOSANE-7-CARBOXYLATE

I. E. Smirnova, E. V. Tret'yakova, O. B. Kazakova, Z. A. Starikova, I. V. Fedyanin
Keywords: methyl-18R-13-isopropyl-10а,7-dimethyl-4-oxo-1-oxahexacyclo[12.4.0.05а,4a.013,12.01,1a.010a,6а]? heneicosane-7-carboxylate, synthesis, X-ray diffraction analysis
Pages: 391-392

Abstract >>
Synthesis is performed and the molecular structure is analyzed of methyl-18R-13-isopropyl-10а,7-dimethyl-4-oxo-1-oxahexacyclo[12.4.0.05а,4a.013,12.01,1a.010a,6а]heneicosane-7-carboxylate II. Compound II С27H40O4 crystallizes in orthorhombic symmetry with cell parameters: а = 11.9915(15) Å, b = 12.1674(16) Å, c = 15.8094(17) Å, space group P212121, Z = 4, d = 1.234 g/cm3.



4398.
MOLECULAR AND CRYSTAL STRUCTURE OF METHYL-4-ANTI-HYDROXYIMINO-1-DIOXOLANO-13-ISOPROPYL-10А,7-DIMETHYLPENTACYCLO×[10B.8.5.04B,10B.06А,10А.01А,4A]ICOS-14-ENE-7-CARBOXYLATE

I. E. Smirnova, E. V. Tret'yakova, O. B. Kazakova, Z. A. Starikova
Keywords: methyl-4-anti-hydroxyimino-1-dioxolano-13-isopropyl-10а,7-dimethylpentacyclo? [10b.8.5.04b,10b.06а,10а.01а,4a]icos-14-ene-7-carboxylate, synthesis, single crystal X-ray diffraction analysis
Pages: 393-395

Abstract >>
Synthesis is performed and the molecular structure is analyzed of methyl-4-anti-hydroxyimino-1-dioxolano-13-isopropyl-10а,7-dimethylpentacyclo[10b.8.5.04b,10b.06а,10а.01а,4a]icos-14-ene-7-carboxylate IIa. Compound IIa С27H40O4 crystallizes in monoclinic symmetry with cell parameters: а = 13.785(13) Å, b = 7.302(7) Å, c = 13.817(13) Å, β = 94.799(19)°, space group Р2(1), Z = 2, d = 1.164 g/cm3.



4399.
NEW POLYMORPHIC MODIFICATION OF THE CRYSTAL STRUCTURE OF BROMOPEGANOL

R. Y. Okmanov, A. G. Tozhiboev, K. K. Turgunov, B. Tashkhodzhaev, N. I. Mukarramov, K. M. Shakhidoyatov
Keywords: alkaloids, quinazolines, polymorphism, X-ray diffraction analysis
Pages: 396-398

Abstract >>
The crystal structure of 6-bromopeganol in a new polymorphic modification is found and determined by single crystal X-ray diffraction analysis. For the crystal structure of the new polymorph the formation of a centrosymmetric closed dimer (associate) is also characteristic. It consists of two bromopeganol molecules bound by centrosymmetric reciprocal hydrogen bonds O-H…N(1). This polymorph differs from the known one in the mutual arrangement and interaction of these associates.



4400.
MOLECULAR AND CRYSTAL STRUCTURE OF 23,24,25,26,27,29,30-HEPTAMETHYL-19,28- OXAHEXACYCLO[15.13.18.017,18.013,14.08,9.05,10]TETRACOS-3-YL ACETATE

N. I. Medvedeva, O. B. Flechter, A. A. Korlyukov
Keywords: 23,24,25,26,27,29,30-heptamethyl-19,28-oxahexacyclo[15.13.18.017,18.013,14.08,9.05,10]tetracos-3-yl acetate, X-ray analysis.
Pages: 399-401

Abstract >>
The molecular structure of 23,24,25,26,27,29,30-heptamethyl-19,28-oxahexacyclo[15.13.18.017,18.013,14.08,9.05,10]tetracos-3-yl acetate III. Compound III С32H52O3 crystallizes in the monoclinic crystal system with the unit cell parameters а = 13.265(15) Å, b = 6.481(7) Å, c = 32.274(4) Å, β = 99.333(2)°, space group С2, Z = 4, d = 1.176 g/cm3.




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