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Humanitarian sciences in Siberia

2011 year, number

6521.
Solovyov's S.M. Approach to Studying Epistolary Sources for Characterizing the Age of Enlightenment in The History of Russia from the Earliest Times

I.V. Prokopyeva
Keywords: "The History of Russia from the Earliest Times" by S.M. Solovyov; epistolary sources; approaches to studying epistolary sources; the Age of Enlightenment; Peter I; the publication, translation and binding of books
Pages: 100-102

Abstract >>
The purpose of the article is to describe S.M. Solovyov's approaches to studying the early XVIII century epistolary sources for characterizing some aspects of the Age of Enlightenment. The special attention is paid to S.M. Solovyov's methods of interpretation of the epistolary sources regarding Peter the Great's activities in the sphere of book publishing, translating and binding at the beginning of the XVIII century. The author reveals the two methods used by S.M.Solovyov for the analysis of historical sources: 1) the source is viewed as a material object; 2) the source is viewed as an information object.



6522.
The Circle of Reading of the Orenburg Province Residents in the ХIХ - early ХХ Centuries

T.N. Savinova
Keywords: circle of reading in a province, library science history, the Orenburg Cossack army, libraries of the Orenburg zemstvo, сulture at the end of the XIX - the beginning of the XX centuries
Pages: 103-106

Abstract >>
The paper deals with questions of the Orenburg province inhabitants' demand for books and periodicals at the end of the XIX - the beginning of the XX centuries which was in direct dependence to the readers' educational level, financial condition, their literary tastes as well as to the form of book distribution - by subscription, through the book trade, libraries. Having studied the information about the library stock of the Orenburg Cossack army the author concludes that for the most part it was composed of the hardcopy fiction lacking scientific and specialized literature; stresses the fact that the demand for periodicals was driven by advertising along with political situation in the country.



6523.
The Russian Television at the Beginning of the ХХI Century: Organizational Structure and Technologies of Broadcast

I.V. Lisunova
Keywords: television, media industry, cable networks, satellite broadcasting, IP-TV, mobile TV, the Internet
Pages: 107-110

Abstract >>
The article is devoted to the problems of con of the new electronic media and development of the existing ones. The author offers classification of the organization structure of the Russian television; describes peculiarities and contradictions in its formation. The main emphasis is placed on revealing the technologies and broadcasting specificity which allows characterizing the current state of the national television industry and foreseeing its further transformations.



6524.
Worship of the Holy Spring Nearby the Village of Ryabovo in the Vikulovskiy District of the Tyumen Region

E.E. Yermakova
Keywords: sacral geography, cultural landscape, worshipped spring, the Ninth Friday, icons, pilgrimage
Pages: 111-113

Abstract >>
The article considers the local tradition of worshipping the holy spring. In this connection the author describes the history of the church in Ryabovo; circumstances of the spring's showing up, pilgrimage to the spring; practice of vowing; cultic attributes.



Thermophysics and Aeromechanics

2011 year, number 2

6525.
Climbing to stars (to the 50th anniversary of Gagarin's space flight)

A.I. Maksimov
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
maksimov@itam.nsc.ru
Keywords: astronautics, cosmonautics, pioneers of rocket engineering, liquid-propellant rocket engine, ballistic missile, launcher, spacecraft, reentry capsule, manned flight
Pages: 163-201

Abstract >>
Development of cosmonautics and preparation to the first manned space flights are briefly observed. Details of the development of the first Soviet intercontinental ballistic missile R-7, which served as a basis for creating Sputnik, Vostok, Voskhod, Molniya, and Soyuz launchers, are given. The contributions of the outstanding designers of space engineering, W. von Braun, S.P. Korolev, V.P. Glushko, and academician M.V. Keldysh, to the development of astronautics and first manned space missions are demonstrated. A list of test launches and manned flights of Vostok and Mercury spacecrafts and the basic characteristics of Vostok, Redstone, Atlas-D, Voskhod, and Soyuz launchers are presented.



6526.
Influence of wind tunnel freestream turbulence level on boundary-layer separation

I.D. Zverkov1, V.V. Kozlov2, A.V. Kryukov2
1 Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
2 Khristianovich Institute of Theoretical and Applied Mechanics SB RAS; Novosibirsk State University
zverkov@itam.nsc.ru
Keywords: wing stall, separation bubble, low Reynolds numbers, wing performance
Pages: 203-214

Abstract >>
An investigation of aerodynamic performance for micro air vehicle (MAV) wing is performed. It is shown, what is a reason of significant wing performance difference between tests, which were carried out in different wind tunnels. New method for estimation of wind tunnel condition influence on experimental results is suggested.



6527.
The effect of thermal prehistory on turbulent separated flow at sudden tube expansion

V.I. Terekhov, T.V. Bogatko
Kutateladze Institute of Thermophysics SB RAS
terekhov@itp.nsc.ru
Keywords: abrupt tube expansion, turbulent flow separation, thermal prehistory
Pages: 215-222

Abstract >>
Results of numerical investigation of the effect of heat boundary layer thickness in front of a sudden expansion of a round tube on turbulent transfer in the zone of flow separation, attachment, and relaxation are presented. Before separation the flow was hydrodynamically stable, and the heat layer in front of expansion could change its thickness in maximally possible limits: from zero to a half of tube diameter. The Reynolds number varied from 6.7∙103 to 1.33∙105. It was found that the growth of heat layer thickness leads to reduction of heat transfer intensity in the separation area and moving away of the coordinate of maximal heat transfer from the place of tube expansion. Generalizing dependence for the maximum Nusselt number is given for variation of the heat layer thickness. Comparison with experimental data of [1] proved the main behavior tendencies of heat and mass transfer processes in separation flows behind a backward-facing step with different thermal prehistory.



6528.
On sufficient stability conditions of the Couette - Poiseuille flow of monodisperse mixture

D.I. Popov, A.M. Sagalakov, N.G. Nikitenko
Altai State University
amsagalakov@mail.ru
Keywords: Couette - Poiseuille flow, interphase interaction, the first Lyapunov method
Pages: 223-233

Abstract >>
The stability of the Couette - Poiseuille flow of a monodisperse mixture is considered. Sufficient stability conditions are derived. Results of the computation of the spectrum are presented. A considerable stabilization of the flow with particles admixture to small disturbances is observed. It is found that the regions of instability generation may have complex geometry. The influence of the main velocity profile and admixture parameters on the stability conditions is considered.



6529.
Deposition of inertial particles from turbulent flow in channels at high Reynolds numbers

D.PH. Sikovsky
Kutateladze Institute of Thermophysics SB RAS; Novosibirsk State University
dphs@itp.nsc.ru
Keywords: turbulence, particle-laden flows, particle deposition, asymptotic theory
Pages: 235-254

Abstract >>
On the basis of the previously developed asymptotic theory of turbulent particle-laden flow with particle deposition in channels coupled with the transport model for the particle Reynolds stress, an asymptotic solution to the problem on the deposition of particles in the limit of high Reynolds numbers was obtained. The numerical calculations confirmed the presence, in the region of the transition from the diffusion-impaction regime of particle sedimentation to the inertia-moderated regime, bifurcation phenomenon of a solution found previously in earlier studies. Features of particle accumulation in the viscous sublayer are analyzed. On the basis of the numerical solution, correlations for particle deposition velocity were obtained. Boundary conditions of the wall-function type for particle concentration whose use allows widening the applicability limits of the equilibrium Eulerian models in terms of particle inertia are proposed.



6530.
Development and experimental investigation of small-sized thermo-electric generator with diffusion combustion

R.V. Fursenko, S.S. Minaev, D.V. Chusov
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
roman.fursenko@gmail.com
Keywords: small-sized energy conversion devices, diffusion combustion, thermoelectricity
Pages: 255-272

Abstract >>
Laboratory samples of small-sized energy converters based on thermo-electric method of heat conversion which source is diffusion microflame are presented in the work. Processes of combustion, energy conversion, and cooling in the proposed systems have been experimentally studied. Relatively high efficiency of the studied systems (energy-conversion 0.8 % at generated electric power of 130 mW) complying with the current world level for such devices is shown. The advantages of the proposed power generators are absence of forced-cooling system and catalysts, assemblage simplicity and usage of available materials and components. On the basis of investigation results, possible ways of further improvement of test samples have been determined with the view of energy conversion efficiency increase.



6531.
Gas filtration and separation with nano-size ceramics

V.I. Lysenko, D.YU. Trufanov, S.P. Bardakhanov
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
vl@itam.nsc.ru
Keywords: nano-size ceramics, filtration, gas separation
Pages: 273-280

Abstract >>
Filtration and separation properties were studied for filters made from open-porosity ceramics (sintered from authors-developed silicon dioxide nanopowder tarkosil". Key parameters were measured for samples of ceramics produced at different sintering temperatures: porosity, gas permeability coefficient, relative time of standard volume fill-up, gas mixture separation coefficient. The possibility of using the described ceramics for helium enrichment was demonstrated with examples of helium-nitrogen and helium-methane mixtures.



6532.
Experimental study of the Taylor bubbles shear stress in an upward flow in a vertical tube

V.E. Nakoryakov, L.S. Timkin, R.S. Gorelik
Kutateladze Institute of Thermophysics SB RAS
timkin@itp.nsc.ru
Keywords: wall shear stress, double shear stress probe, slug flow, Taylor bubble, and electro-diffusional method
Pages: 281-292

Abstract >>
The modification of electrodiffusional method of the wall shear stress measurements is applied for registration of the Taylor bubble shear stress in an upward liquid flow. Time realization of shear is considered as a structure frozen into the flow, which moves together with a bubble. Experiments were carried out in laminar and transitional liquid flows. The wall shear stress in the liquid film around bubble averaged over the tube perimeter is presented for different flow Reynolds numbers and different lengths of the bubble.



6533.
Formation of dynamic spatial flame structures for gas burning in microchannels with temperature gradients on walls

E.V. Sereshchenko1, R.V. Fursenko1, S.S. Minaev1, V.N. Kurdyumov2
1 Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
2 Energy Department of CIEMAT
minaev@itam.nsc.ru
Keywords: microcombustion, instability, ignition
Pages: 293-304

Abstract >>
The thermal-diffusive model was applied to the problem of flame propagation in a microchannel with controlled temperature distribution in the walls; this demonstrated the possibility of formation of oscillating or rotating spatial flame structures, which were described previously in experimental works on microcombustion. Two cases were considered: combustion in a rectangular channel and in the clearance between two disks with radial feeding of premixture. In both cases, the typical across size of the channel was lower than the critical diameter determined with respect to the ambient temperature. The gas flow was assigned and described by the Poiseuille-flow velocity profile. Formation of oscillating flame in a rectangular channel and rotating patterns in a radial channel was observed for a certain range of gas flow rate. At low flow rates beyond this range, repetitive ignition/extinction of flame took place; at high flow rate we observed a steady flame mode. Formation of these special flame structures is related to heat transfer between gas and hot walls of the channel, as well as to velocity maldistribution in the microchannel.



6534.
Radiation processes in impulse cesium plasma of high pressure

S.V. Gavrish
Closed Corporation SKB ZENIT
svgavr@list.ru
Keywords: impulse discharge, plasma, cesium, xenon, mercury, quasi-stationary discharge, spectral distribution, vapor pressure, plasma absorption factor
Pages: 305-311

Abstract >>
Dependence of spectral and energy characteristics of cesium plasma radiation on electric power PL has been found. It is shown that with PL growth metal vapor pressure increases; transformation of spectral structure of radiation manifested in disappearance of individual lines and increase of steady monotone takes place. Redistribution of average radiation power in individual spectral ranges is observed.



6535.
Study of slag content and properties after plasma melting of incineration ash

Hyun-seo park
Jeonju University
hnsepark@unitel.co.kr
Keywords: plasma melting, incineration ash, dioxins, environment, chemical compound, heavy metals, leaching
Pages: 313-321

Abstract >>
The paper presents the investigation of plasma melting of the mixed bottom and fly incineration ash at various mixing ratios of the components. Chemical compound of the bottom and fly ash as well as the slag after its melting was analyzed by different methods, and the content of toxic components in them was determined. It is demonstrated that the direct disposal of the fly and bottom incineration ash may cause dioxin and heavy metal contamination of the environment. The influence of melted ash basicity on the resulting slag compound was studied. The mass balance of the melting process was defined. The tests were performed to determine the heavy-metals leaching from the ash and slag. It is also shown that the slag after plasma melting is dioxin-free and environmentally friendly.



6536.
Efficiency of vapor compression heat pumps based on non-azeotropic refrigerant mixtures

N.N. Mezentseva
Kutateladze Institute of Thermophysics SB RAS
mezn@itp.nsc.ru
Keywords: non-azeotropic refrigerants, heat pump, energy conversion ratio
Pages: 323-330

Abstract >>
The work presents the results of cycle computation for vapor compression pumps based on ozone-safe mixed refrigerants. Non-azeotropic binary refrugerants R32/R152а (30/70) and R32/R134а (30/70) were considered as working substances. Properties of non-azeotropic refrigerants were calculated according to the additivity method of thermodynamic functions and method of Lemmon and Jacobsen. Deviations in the values of thermophysical properties obtained with two methods have been determined. It is shown that at the use of non-azeotropic mixture R32/R152a (30/70), energy conversion ratio increases by 2.2−3.6 % compared with the results for R32/R134a (30/70) at temperature difference between the processes of boiling and condensation from 28 to 53 °С.



6537.
80th Anniversary of Vladimir B. Kurzin

Editorial board
Siberian Branch of the RAS
Pages: 331-332

Abstract >>
On April 13, 2011 Chief researcher of Lavrentiev Institute of Hydrodynamics SB RAS, Doctor of Physics and Mathematics, Professor Vladimir B. Kurzin  was  80 years of age.



6538.
Interferometric technique for measurement of droplet diameter

A.V. Bilsky1, YU.A. Lozhkin1, D.M. Markovich2
1 Kutateladze Institute of Thermophysics SB RAS
2 Kutateladze Institute of Thermophysics SB RAS; Novosibirsk State University
dmark@itp.nsc.ru
Keywords: droplet diameter, interferometer, laser, gas-droplet flow, IPI
Pages: 1-12

Abstract >>
The paper considers the optical contact-free method of droplet diameter sizing in the flow cross-section utilizing light interference on a droplet. Distribution of light scattered by a particle was analyzed for different configurations of the measurement system using the Mie theory and approximation of geometrical optics. Basic measurement errors and dynamic range were determined. Possibility of measurements with camera mounting at the angle of 90º to the plane of a laser sheet is shown; this simplifies setup calibration and evens characteristics over the image field. The procedure of measurement system calibration and a set of algorithms for data processing are suggested. The suggested approaches were applied for measurement of characteristics of the gas-droplet jet.



6539.
Hydrodynamics, heat and mass exchange in sprayer sprinkling chambers

M.I. Shilyaev, E.M. Khromova, A.V. Grigoriev, A.V. Tumashova
Tomsk State University of Civil Engineering
shmi@mail.tomsknet.ru
Keywords: liquid droplets, heat and mass exchange, moisture content, steam and gas flow, sprayer sprinkling chambers
Pages: 13-24

Abstract >>
A two-dimensional physical and mathematical model of the motion and heat and mass exchange of a steam and gas mixture with liquid droplets of variable mass in sprayer sprinkling chambers at high moisture contents is formulated by using the concepts of interpenetrating continua with different velocities and temperatures. An analysis of this model is carried out.



6540.
Investigation of acoustic waves propagation and flow in nanodispersed medium

S.P. Bardakhanov, V.I. Lysenko, V.V. Obanin, D.YU. Trufanov
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
bard@itam.nsc.ru
Keywords: nanodisperse powder, flow, acoustic waves
Pages: 25-30

Abstract >>
Propagation of acoustic waves in nanodisperse powders and powder flow under the influence of acoustic vibrations have been investigated in the horizontal tube with the use of visualization and hot-wire anemometer methods.



6541.
Boiling-up of liquid argon at high superheatings under the impact of weak ultrasonic fields

V.G. Baidakov, A.M. Kaverin, V.N. Andbaeva
Institute of Thermophysics UB RAS
baidakov@itp.uran.ru
Keywords: acoustic cavitation, nucleation, superheat, boiling-up, argon
Pages: 31-36

Abstract >>
The technique of lifetime measurement for metastable liquid and continuous depressurization technique were applied for study of kinetics of spontaneous cavitation in superheated liquid argon under impact of weak ultrasonic fields. It was demonstrated that acoustic cavitation may occur through the mechanism of homogeneous generation of vapor phase or through swinging of vapor bubbles generated by high-energy particles and/or other kinds of initiative factors. The thresholds of acoustic cavitation are described by the theory of homogeneous nucleation.



6542.
Local characteristics of the upward bubbly flow in an annular channel

O.N. Kashinsky, A.S. Kurdyumov, P.D. Lobanov
Kutateladze Institute of Thermophysics SB RAS
kurdumov@itp.nsc.ru
Keywords: bubbly flow, annular channel, void fraction, wall shear stress, electrochemical method
Pages: 37-41

Abstract >>
Results of experimental investigation of the bubbly gas-liquid flow in a vertical annular channel are presented. The average and pulsation shear stresses and distributions of local void fraction were measured by the electrochemical method on both channel walls. It is shown that with a rise of gas flow rate ratio the value of wall shear stress increases significantly, and this effect becomes higher at a decrease in superficial liquid velocity. A presence of the gas phase effects significantly shear stress on the inner wall. Relative intensity of shear stress pulsations increases similarly on both channel walls.



6543.
Development and experimental investigation of small-sized thermo-electric generator with diffusion combustion

R.V. Fursenko, S.S. Minaev, D.V. Chusov
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
roman.fursenko@gmail.com
Keywords: small-sized energy conversion devices, diffusion combustion, thermoelectricity
Pages: 43-50

Abstract >>
Laboratory samples of small-sized energy converters based on thermo-electric method of heat conversion which source is diffusion microflame are presented in the work. Processes of combustion, energy conversion, and cooling in the proposed systems have been experimentally studied. Relatively high efficiency of the studied systems (energy-conversion 0.8 % at generated electric power of 130 mW) complying with the current world level for such devices is shown. The advantages of the proposed power generators are absence of forced-cooling system and catalysts, assemblage simplicity and usage of available materials and components. On the basis of investigation results, possible ways of further improvement of test samples have been determined with the view of energy conversion efficiency increase.



6544.
The effect of scratch technique on the thermal-product value of temperature sensors

H.A. Mohammed, H. Salleh, M.Z. Yusoff
College of Engineering, Universiti Tenaga Nasional
Hussein@uniten.edu.my
Keywords: temperature sensor, thermal product, junction surface, shock tube
Pages: 51-64

Abstract >>
The effect of different scratch techniques, mainly abrasive papers and scalpel blades used to form the junctions of temperature sensors, on the thermal-product value of these sensors, was examined. A dynamic calibration procedure of scratched sensors in a shock tube facility which allows easy evaluation of their thermal-product value is outlined. The thermal product of a particular sensor was found to be dependent on the flow Mach number, junction scratch technique, junction location, and also on the enthalpy conditions. It was shown that using different scratch techniques normally results in different thermal-product values of sensors. The experimental procedure used in the present study has yielded practical data on characteristics of scratched temperature sensors; these data can be used in accurate measurement of transient heat transfer under hypersonic flow conditions.



6545.
Flow fluctuation measurement in the flow-through path of continuous electric-discharge СО2−laser contour

V.N. Zinoviev, V.A. Lebiga, A.YU. Pak, YU.V. Afonin, A.M. Orishich
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
lebiga@itam.nsc.ru
Keywords: gas laser, air gap, velocity fluctuations, hot-wire anemometer
Pages: 65-71

Abstract >>
We have experimentally proved the applicability of hot-wire anemometer method to measure fluctuations at low pressures and gas flow rates when medium is no longer considered as continuous. Use of individual calibration at working conditions serves to apply standard technique for determination of sensitivity coefficients of hot-wire probes. Additional investigations are necessary to take into account influence of Knudsen number and, possibly, other parameters in heat transfer law presented as criterial dependence of Nusselt number on Reynolds number. Hot-wire measurement of mean velocity distribution and their fluctuations in the flow-through path of electric-discharge CO2 laser have been performed. The level of velocity fluctuations in the vicinity of anode is high that is caused by the zone of interacting flows from the ventilators rotating in opposite directions forming in the symmetry plane. Placing of the damping screen between the ventilator and air gap allows decreasing fluctuations intensity to the acceptable level. It has been ascertained that the vortex shedding with high intensity of fluctuations which influence is noticeable in significant part of air gap is formed in the wake behind the streamlined cathode. However, pulsation level in the proper gap does not exceed permissible values.



6546.
Investigation of turbulence models for computation of swirling flows

A.V. Sentyabov1, A.A. Gavrilov2, A.A. Dekterev1
1 Krasnoyarsk Department of the Institute of Thermophysics SB RAS; SiberianFederal University
2 Krasnoyarsk Department of the Institute of Thermophysics SB RAS
sentyabov_a_v@mail.ru, gavand@yandex.ru
Keywords: swirling flows, eddy precession, turbulence models, method of modeling of detached eddies
Pages: 73-85

Abstract >>
Different turbulence models were studied in application to calculation of swirling flows. The differential models of turbulent viscosity considering streamline curvature and the method of detached eddy simulation were used. Weakly and strongly swirling flows were considered at the example of concentrated vortex in a tube, swirling flow in a diffuser, and vortex breakdown through an abrupt expansion. The RANS models with correction to flow swirling represented well the experimental data for the weakly swirling flows. In case of strongly swirling flows, it was more correct to use the method of detached eddy simulation.



6547.
Design of supersonic three-dimensional inlets using two-dimensional isentropic compression flow

YU.P. Goonko, I.I. Mazhul
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
gounko@itam.nsc.ru, mazhul@itam.nsc.ru
Keywords: three-dimensional (3D) inlets, two-dimensional (2D) flows, gasdynamic design, supersonic velocities, design and off-design flow regimes
Pages: 87-100

Abstract >>
The design of supersonic three-dimensional inlets using the V-shaped body forming a two-dimensional flow including an initial oblique shock wave and a subsequent isentropic compression wave is considered. Such a flow appears attractive for inlets design due to a possibility of obtaining high compression levels of external flow over the inlet ramp with small losses of the total pressure. Numerical computations of the flows around the designed configurations were carried out in design and off-design regimes using Euler code. The flow structure was identified, the aerodynamic characteristics of the inlets were determined. The investigation covers the range of supersonic speeds corresponding to the freestream Mach numbers М = 1.8−2.5.



6548.
Transient growth of stationary flow perturbations at laminar boundary-layer separation

A.V. Boiko1, A.V. Dovgal1, A.M. Sorokin2
1 Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
2 Khristianovich Institute of Theoretical and Applied Mechanics SB RAS; Novosibirsk State University
dovgal@itam.nsc.ru
Keywords: hydrodynamic instability, flow separation, transient growth, aerodynamic experiment
Pages: 101-106

Abstract >>
In a subsonic wind tunnel, laminar boundary-layer separation at a backward-facing step on a flat plate modulated by stationary flow perturbations was examined. The stationary disturbances were introduced into the flow by controlled roughness elements spaced on the model surface close to the separation line. Through a comparison of obtained data with results gained in previous studies of other periodic roughness systems, some trends in the generation of stationary disturbances subject to transient growth in separation region were revealed.



6549.
Mathematical simulation of conjugate turbulent natural convection in an enclosure with local heat source

M.A. Sheremet
Tomsk State University
Michael-sher@yandex.ru
Keywords: conjugate heat transfer, natural convection, turbulence, local heat source, rectangular region, numerical modelling
Pages: 107-121

Abstract >>
A numerical analysis of turbulent regimes of the natural convection in a closed rectangular region with heat-conducting walls of finite thickness was carried out in the presence of a locally concentrated heat source under the conditions of the radiative-convective heat exchange with the ambient medium on one of the external boundaries. The mathematical model was constructed on the basis of the Reynolds equations in dimensionless variables stream function − vorticity vector − temperature. Special attention was paid to the investigation of the influence of the Grashof number 10^8<Gr<10^10, of the unsteadiness factor , and the thermal conductivity ratio a2,1=5.7*10^-4, 6.8*10^-5 on both the local and integral characteristics of the problem.



6550.
Structure parameters and structure sensitive properties of Sn0.739Pb0.261 melt

V.M. Sklyarchuk1, YU.A. Plevachuk1, A.S. Yakimovich1, I.I. Shtablavy1, S.V. Stankus2, R.A. Khairulin2
1 Ivan Franko Lviv National University
2 Kutateladze Institute of Thermophysics SB RAS
sklyarchuk@ukr.net, kra@itp.nsc.ru
Keywords: structure factor, interdiffusion, viscosity, Sn?Pb eutectic, melt
Pages: 123-128

Abstract >>
Structure, interdiffusion, and dynamic viscosity of eutectic Sn−Pb melt have been experimentally investigated in a wide temperature range. On the basis of the obtained data on the position and form of the first maximum of the structure factor in the framework of the hard sphere model, values of sphere packing index and sphere diameter have been determined for the melt at 470 and 570 K. Correlations resulting from the model of hard spheres served to calculate coefficients of dynamic viscosity and interdiffusion of liquid alloy. Besides, temperature dependence of dynamic viscosity has been calculated with the use of thermodynamic approximation of Kozlov ⎯ Romanov ⎯ Petrov. Calculated values of the properties have been compared with experimental data.



6551.
Effect of hydrothermal conductivity on thermal resistance of porous materials

S.S. Efimov, E.G. Starostin, N.I. Tappyrova
Institute of Physical-Technical Problems of the North SB RAS
e.g.starostin@iptpn.ysn.ru
Keywords: porous material, hydrothermal conductivity, moisture, thermal resistance, thermogradient coefficient
Pages: 129-134

Abstract >>
Results of experimental study for dependency of thermogradient coefficient on moisture in porous material have been presented. These experimental data were used for estimating the effect of hydrothermal conductivity on heat transfer.



6552.
Modelling of thermal conductivity in hybrid composites made from binding matrix, with orthogonal reinforcement with tubes and with disperse-hardened hollow inclusions

A.P. Yankovsky
Khristianovich Institute of Theoretical and Applied Mechanics SB RAS
nemirov@itam.nsc.ru
Keywords: thermal conductivity, composites, hollow fibers, disperse inclusions, generalization of Fourier's law, Stephan ? Boltzmann law
Pages: 135-150

Abstract >>
The models were developed for thermal conductivity of a binding medium reinforced with tubes and with disperse-hardened hollow inclusions; the models have versions with/without consideration of relaxation times of materials making the phases of composition. For a limiting case, when tubes degenerate into solid fibers, we compared calculated values for efficient thermal conductivity coefficients for the case of single-direction and crisscross reinforced composites with corresponding experimental values. A satisfactory agreement between theory and experiment takes place.



6553.
Thermal conductivity of refrigerant 507A in gaseous state

O.I. Verba
Kutateladze Institute of Thermophysics SB RAS
gamma@itp.nsc.ru
Keywords: thermal conductivity, refrigerant, R 507A, method of coaxial cylinders
Pages: 151-154

Abstract >>
Thermal conductivity of refrigerant 507А in gaseous state has been measured with a stationary method of coaxial cylinders in the temperatures range of 315 - 425 K and pressures 0.105 - 1.855 MPa. Estimated values of temperature, pressure, and thermal conductivity measurement errors are, respectively, ± 0.05 K, ± 3.75 kPa and ± 1.5 − 2.5 %. Approximation dependence for thermal conductivity in the whole studied temperature and pressure range has been obtained. Results have been compared with available literature data.



6554.
80th Anniversary of Anatoly M. Kharitonov

Editorial board
Siberian Branch of the RAS
Pages: 155-156

Abstract >>
16 January, 2011  was the 80th anniversary of the Doctor of Technical Sciences, the Honored Worker of Russian Science, winner of the Award of the Council of Ministers of the USSR, Professor Anatoly Mikhailovich Kharitonov.



6555.
75th Anniversary of Vyacheslav N. Yarygin

Editorial board
Siberian Branch of the RAS
Pages: 157-158

Abstract >>
30 December, 2010  was the 75th anniversary of the Doctor of Technical Sciences, the Honored Worker of Russian Science, winner of the USSR State and of the Award of the Council of Ministers of the USSR, Professor Vladimir Kostantinovich Baev.



2011 year, number 4

6556.
A SIMPLE ORBITAL BASIS SET FOR Π ELECTRON CALCULATIONS OF THE POLARIZABILITIES AND HYPERPOLARIZABILITIES OF CONJUGATED SYSTEMS

A. B. Zakharov, V. V. Ivanov
Keywords: polarizability, hyperpolarizability, CCSD method, FCI method
Pages: 667-673

Abstract >>
Within the theory of coupled clusters, it is proposed to use the orbital basis set of ethylene molecules in the π electron calculations of the polarizabilities and hyperpolarizabilities of conjugated systems. Test calculations show high accuracy of the method in comparison with the full configuration interaction method.



6557.
METHANOL INTERACTION WITH POTASSIUM AND RUBIDIUM HYDROXIDES IN DIMETHYL SULFOXIDE

N. M. Vitkovskaya, E. Y. Larionova, N. V. Kaempf, V. B. Kobychev, B. A. Trofimov
Keywords: methanol, alkali metal hydroxide, vinylation, reaction mechanisms, quantum chemical calculations
Pages: 674-680

Abstract >>
A comparative ab initio quantum chemical study of methanol interaction with potassium and rubidium hydroxides surrounded by DMSO molecules is performed. The reaction profiles of the formation of a nucleophilic particle in the direct interaction of methanol with an undissociated molecule of alkali metal hydroxide are considered. The levels of the description of the reacting system by different cluster continuum models are compared.



6558.
INTERACTION OF METHANOL, METHANTHIOL, AND ACETOXIME WITH POTASSIUM AND RUBIDIUM HYDROXIDES IN DIMETHYL SULFOXIDE

N. M. Vitkovskaya, E. Y. Larionova, N. V. Kaempf, V. B. Kobychev, A. D. Skitnevskaya, V. B. Orel, B. A. Trofimov
Keywords: methanol, methanthiol, acetoxime, alkali metal hydroxide, vinylation, reaction mechanisms, quantum chemical calculations
Pages: 681-685

Abstract >>
An ab initio quantum chemical study of the reaction profiles of the nucleophile particle formation in the interaction of methanol, methanthiol, and acetoxime with an undissociated molecule of alkali metal hydroxide is performed for the gas phase and also with the explicit inclusion of a dimethyl sulfoxide molecule into the calculation and with allowance made for solvation effects within the continuum model.



6559.
A COMPARATIVE STUDY OF INTERMOLECULAR POTENTIAL ENERGY FUNCTIONS PROPOSED FOR THE RARE GAS DIMERS

R. Islampour, M. Gharibi, A. Khavaninzadeh
Department of Chemistry Tarbiat Moallem University
islampour@tmu.ac.ir
Keywords: rare gas dimers, DVR method, vibration-rotation energy levels
Pages: 686-695

Abstract >>
The vibration-rotation energy level spacings of homo- and heteronuclear rare gas dimers are calculated for some more common analytical intermolecular potential energy functions in
a unified way by employing the discrete variable representation (DVR) method.



6560.
FIRST-PRINCIPLES STUDY ON THE MRh12 (M = Rh, Fe, Co, AND Ni) CLUSTERS

X. Kuang1, X. Wang2, G. Liu2
1 College of Mathematics and Physics Chongqing University School of Science, Southwest University of Science and Technology
2 College of Mathematics and Physics Chongqing University
xkdkxj@yahoo.com.cn
Keywords: MRh12 cluster, geometrical structure, electronic and magnetic properties
Pages: 696-703

Abstract >>
In this paper, a first-principles study on the stability, electronic and magnetic properties of MRh12 (M = Rh, Fe, Co and Ni) clusters is performed. By optimizing the geometrical structure, we find that MRh12 clusters change from a perfect icosahedron to a distorted structure and have an obvious bond length contraction as compared with the corresponding bulk phase; FeRh12, CoRh12, and NiRh12 clusters are more energetically stable than the RhRh12 cluster. The effect of the impurity M on the density of states, valence band width, HOMO and LUMO for MRh12 clusters is not significant, but when the central Rh atom is substituted with M, the magnetic moment of MRh12 reduces dramatically. The Mulliken population analysis indicates that there are more charge transfers from other orbitals to Rh4d and M3d orbitals, and the spd hybrid effect in d orbitals of MRh12 clusters is stronger than that in the RhRh12 cluster. this situation means that the unpaired d electrons have more chance to be paired, and the magnetic moments of MRh12 clusters can be reduced reasonably.




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