NANOPOROUS solvate of N,N-phthaloyl-glycine
N. A. Tumanov, N. A. Pankrushina, A. A. Nefedov, E. V. Boldyreva
Keywords: nanoporous solvate of N, N-phthaloyl-glycine, crystal structure, thermogravimetry, high-resolution mass spectrometry
Pages: 611-614
Abstract
N,N-phthaloyl-glycine is synthesized under microwave activation without solvent. Its nanoporous solvate is obtained by recrystallization. The solvate is studied by single crystal and powder XRD, thermogravimetry, and mass spectrometry. The crystals are composed of dimers that form a framework structure with infinite channels of about 4 Å in diameter, containing a non-stoichiometric amount of chloroform (the mole fraction is close to 0.35). The nature of the incorporated solvate molecules is determined by high-resolution mass spectrometry, and their quantity is found by thermogravimetry.
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