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Journal of Structural Chemistry

2012 year, number 1

CRYSTAL AND MOLECULAR STRUCTURE OF THE COMPLEX OF 2-(1-SILATRANYLMETHYLTHIO)-4,5-BENZO-1,3-THIAZOLE WITH СоСl2 AND MeCN

M. G. Voronkov, Г‰. A. Zel'bst, A. D. Vasiliev, A. S. Soldatenko, Y. I. Bolgova, O. M. Trofimova
Keywords: 2-(1-silatranylmethylthio)-4, 5-benzo-1, 3-thiazole, acetonitrile, molecular structure, single crystal X-ray diffraction analysis
Pages: 196-199

Abstract

The crystal and molecular structure of the complex of 2-(1-silatranylmethylthio)-4,5-benzo-1,3-thiazole with СоСl2 and MeCN (I) is determined by single crystal X-ray diffraction. The geometry of the silatranylmethyl moiety in complex I is compared to the geometry of 1-(2′-benzthiazolylthiomethyl)silatrane. Molecular packing in the crystal is analyzed.