CRYSTAL STRUCTURE OF A COMPLEX OF NICKEL(ii) WITH 2-AMINO-4-IMINO-2-PENTENE
S. I. Dorovskikh, K. V. Zherikova, N. V. Kuratieva, N. B. Morozova
Keywords: nickel(II), ?-diimine, X-ray crystallography
Pages: 1157-1160
Abstract
The structure of a nickel(II) complex with 2-amino-4-iminopentane is determined by X-ray crystallography at 150 K. Crystal data for C10H18N4Ni are: a = 10.9802(3) Å, b = 13.5780(4) Å, c = 8.0935(2) Å, β = 107.304(1)°, space group P21/c, V = 1152.04(5) Å3, Z = 4, dx = 1.459 g/cm3, R = 0.0283. The structure is molecular; the metal atom is coordinated by four nitrogen atoms of two β-diimine ligands. The Ni-N distances in Ni(NacNac)2 fall within 1.8571-1.8623 Å. The molecules in the crystal are joined by only van der Waals interactions.
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