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Journal of Structural Chemistry

2011 year, number 4


A. A. Rybinskaya, E. A. Shusharina, P. E. Plyusnin, Y. V. Shubin, S. V. Korenev, S. A. Gromilov
Keywords: palladium, iridium, double complex salt, single crystal X-ray diffraction, powder X-ray diffraction, thermal analysis
Pages: 836-839


A single crystal of [Pd(NH3)4]3[Ir(NO2)6]2·H2O double complex salt is studied by X-ray diffraction. Crystallographic characteristics are as follows: a = 21.0335(5) Å, b = 8.0592(2) Å, c = 21.3452(5) Å, β = 91.254(1)°, V = 3617.43(15) Å3, P21/с space group, Z = 4, dx = 2.714 g/cm3. Single-layer pseudo-hexagonal packing of complex anions is determined along the [-1 0 1] direction in the structure. Complex cations and crystallization water molecules are located between the mentioned layers.