Structure and Luminescence of [Tb0.5(C6NO2H5)3(H2O)2]2n·(H3O)4n(ZnCl5)n(ZnCl4)2n
W.-T. Chen, S.-M. Ying, Y.-P. Xu, Q.-Y. Luo, D.-S. Liu
College of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University
cwtqq@yahoo.com.cn
Keywords: crystal structure, terbium, lanthanide, photoluminescence
Pages: 645-648
Abstract
A novel bimetallic 4f-3d metal-isonicotinic acid inorganic-organic hybrid complex [Tb0.5(C6NO2H5)3(H2O)2]2n·(H3O)4n(ZnCl5)n(ZnCl4)2n (1) is synthesized. It has a one-dimensional polycationic chain-like structure. Photoluminescent investigation reveals that it displays interesting emissions in the violet, blue, green, and yellow regions.
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