AN X-RAY DIFFRACTION STUDY OF THE REACTION PRODUCTS OF COPPER(II) CHLORIDE WITH N1,N2-BIS(5-METHYLPYRIDIN-2-YL)OXALAMIDE
D. A. Piryazev, A. S. Zhilin, A. I. Smolentsev, A. V. Virovets, S. F. Vasilevskii, L. G. Lavrenova
Keywords: N1, N2-bis(5-methylpyridin-2-yl)oxalamide, complexes, coordination polymers, copper(II), singe crystal and powder XRD
Pages: 383-389
Abstract
Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2-yl)-oxalamide)) and {[Cu2(C2O4)Cl2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.
|
