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Journal of Structural Chemistry

2011 year, number 1

DIELECTRIC PROPERTIES OF A DIPOLAR HARD SPHERE LIQUID: ASSOCIATION EQUILIBRIA THEORY

G. B. Litinskii
Keywords: association equilibria theory, association constant, Kirkwood factor, dipolar hard sphere fluid
Pages: 96-100

Abstract

The hindered rotation model is used to generalize the association equilibria theory for the case of a dense dipolar hard sphere (DHS) liquid. The derived expressions for the orientation constant of association and the Kirkwood factor of a DHS liquid are well consistent with machine experiments in the high temperature region.