Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia

Advanced Search

Journal of Structural Chemistry

2010 year, number 6

crystal structure and Fluorescence of a new 2D layerED cadmium(II) malate Coordination Polymer

G.-H. Cui, G.-Y. Dong, X.-H. Liu, Y.-M. Yu
Keywords: cadmium(II), crystal structure, malate ligand, coordination polymer, two-dimension, fluorescence
Pages: 1230-1234


A new two-dimensional layered cadmium coordination polymer [Cd(D,L-mal)H2O]n (H2mal =
= malic acid) is solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Each Cd(II) centre is surrounded by seven oxygen atoms from three different malate ligands and one coordinated water molecular forming a pentagonal bipyramidal configuration. Furthermore, complex 1 exhibits blue intense photoluminescence property at room temperature.