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Journal of Structural Chemistry

2010 year, number 3

TWo CRYSTALLINE MODIFICATIONS OF [Au(dien)Cl](ReO4)2: SYNTHESIS, Structure, AND THERMAL PROPERTies

I. A. Baidina, E. V. Makotchenko, E. A. Shusharina, P. E. Plyusnin, A. I. Smolentsev, S. A. Gromilov
Keywords: gold, rhenium, complex, crystal chemistry, single crystal X-ray diffraction analysis, thermal analysis
Pages: 544-551

Abstract

Two crystalline modifications of a new [Au(dien)Cl](ReO4)2 complex are studied. The geometric characteristics of the [Au(dien)Cl]2+ complex cations are compared, and the way of additional coordination of gold atomоs is considered. The thermal properties of the compound are studied in the inert and reducing atmospheres, and for the first time the possibility of the formation of Au0.1Re0.9 solid solution based on the hcp lattice of Re is shown.