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Journal of Structural Chemistry

2010 year, number 3

CRYSTAL CHEMICAL FEATURES OF DAVYNE FROM TULTUI LAZURITE DEPOSIT (BAIKAL REGION)

A. N. Sapozhnikov
Keywords: cancrinite group, davyne structure, anion complexes, sulfate and sulfide forms of sulfur
Pages: 525-531

Abstract

The study shows that in the structure of davyne from the Baikal region sulfur exists in two forms: sulfate and sulfide. The presence of  disulfide makes it possible to remove charge imbalance in the chemical formula that emerged mainly because all sulfur was presented in the mineral only in the sulfate form. So far, sulfide sulfur has not been observed in the minerals of the davyne subgroup.