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Journal of Structural Chemistry

2010 year, number 1

FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl]Г—[Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O

M. A. Il'in, V. A. Emel'yanov, I. A. Baidina
Keywords: ruthenium, nitroso complexes, ammine complexes, chloro complexes, single crystal X-ray diffraction analysis, IR spectroscopy
Pages: 105-112

Abstract

The structure of the interaction products of (NH4)2[Ru(NO)Cl5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl]×
[Ru(NO)(NH3)Cl4]2Cl·2H2O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) Å, b = 8.202(2) Å, c = 11.844(2) Å; β = 101.54(3)°.