THEORETICAL STUDY OF THE CONFORMATIONAL FEATURES OF TRIOSMIUM CLUSTERS
V. A. Potemkin, N. N. Ivshina, V. A. Maksakov
Keywords: conformational analysis, cluster complexes, osmium
Pages: 150-158
Abstract
The article summarizes the results of the study of conformational states of triosmium clusters with organic ligands. Special attention is paid to the structural features of molecular carbonyl cluster complexes with Mn(CO)mL organic ligands. The effect of the structure surface charge, solvent, cluster crystalline state, and intermolecular and intramolecular interactions on the cluster conformational state is also determined.
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