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Journal of Structural Chemistry

2009 year, number 6

FREE ELECTRON MODEL FOR HETEROATOMIC CONJUGATE MOLECULES

G. B. Litinskii, V. E. Krikunova
Keywords: free electron model, heteroatomic conjugate molecules, energy spectrum
Pages: 1078-1083

Abstract

A simple generalization of the free electron model is suggested for describing the heteroatomic conjugate molecules and obtaining analytical equations for the energy levels of these systems. The δ-like potential is used as a potential of a heteroatom in this model, and the energy levels are obtained as corrections for first order perturbation theory.