MOLECULAR AND CRYSTAL STRUCTURE OF 2,4-DIETHOXYCARBONYL-5-HYDROXY- 5-METHYL-3-PHENYL-N-(3-CHLOROPHENYL)-1-CYCLOHEXENYLAMINE
A. P. Kriven'ko, Г‰. A. Grigor'eva, A. V. Grigor'ev, V. V. Sorokin, S. F. Solodovnikov
Keywords: X-ray structural analysis, enaminoesters, cyclohexenes
Pages: 963-966
Abstract
Arylamination of 2,4-diethoxycarbonyl-5-hydroxy-5-methyl-3-phenylcyclohexanone affords 2,4-diethoxycarbonyl-5-hydroxy-5-methyl-3-phenyl-N-(3-chlorophenyl)-1-cyclohexenylamine. A distorted semi-chair conformation with psedoequatorial orientation of all substituents except the pseudoaxial ОН-group is established based on the spectral and single crystal XRD data. The presence of an intramolecular N-Н…О=C hydrogen bond is noted.
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