STRUCTURE OF [RuNO(NH3)3(H2O)Cl](NO3)2, PRODUCT OF INTERACTION BETWEEN HYDROXONITROTRIAMMINENITROSORUTHENIUM(II) CHLORIDE AND NITRIC ACID
V. A. Emel'yanov, E. V. Kabin, I. A. Baidina
Keywords: ruthenium, nitroso complexes, ammine complexes, X-ray diffraction analysis, crystal chemistry
Pages: 598-601
Abstract
The structure of the product formed on boiling [RuNO(NH3)3(NO2)(ОH)]Cl·0.5H2O in 3 M HNO3 is determined by XRD. The crystals belong to monoclinic symmetry. Crystallographic data for H11ClN6O8Ru are: a = 13.7924(4) Å, b = 6.9114(2) Å, c = 12.3577(4) Å, β = 111.863(1)°, V = 1093.27(6) Å3, Z = 4, dcalc = 2.185 g/cm3, space group Cc. The structure is built of complex [RuNO(NH3)3(H2O)Cl]2+ cations and anions NO-3. The compound is studied by IR spectroscopy and X-ray phase analysis.
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