CRYSTAL STRUCTURE OF THE BIOCTAHEDRAL CLUSTER COMPLEX K6[Re12Cs17(CN)6]·2CH3OH·10H2O
Y. V. Mironov, S.-J. Kim, V. E. Fedorov
Keywords: rhenium, bioctahedral thiocyanate cluster, synthesis, crystal structure
Pages: 378-380
Abstract
The cluster complex of K6[Re12CS17(CN)6]·2CH3OH·10H2O composition is separated by recrystallization of the K6[Re12CS17(CN)6]·20H2O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) Å, c = 14.631(4) Å, V = 1531.3(5) Å3, Z = 1, and dcalc = 3.720 g/cm3.
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