CRYSTAL STRUCTURE OF Cs[Gd(H2O)4Re6Te8(CN)6]в‹…4H2O
M. S. Tarasenko, N. G. Naumov, A. V. Virovets, S.-J. Kim, V. E. Fedorov
Keywords: rhenium, octahedral cluster, cyanide complex, gadolinium, crystal structure
Pages: 1167-1170
Abstract
The structure of the salt Cs[Gd(H2O)4Re6Te8(CN)6]⋅4H2O (space group P-1, a = 9.436(5) Å, b =
12.365(7) Å, c = 15.187(8) Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re6Te8(CN)6]4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.
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