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Journal of Structural Chemistry

2008 year, number 5

Dielectric properties of a liquid of dipole hard spheres

G. B. Litinskii
Keywords: Kirkwood factor, dielectric permittivity, polar liquids, dipole hard spheres
Pages: 907-911


The Kirkwood factor gK of a model polar liquid of dipolar hard spheres (DHSs) was approximated by analytical equations using the approximation of the interaction of the second neighbors within the hindered rotation model. The derived equations describe the temperature and density dependences of the dielectric functions of the DHS liquid.