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Journal of Structural Chemistry

2008 year, number 4

CRYSTAL STRUCTURE OF Tl5{[Nb2S4Br8]Br}

A. L. Gushchin, M. N. Sokolov, E. V. Peresypkina, V. P. Fedin
Keywords: cluster, thallium, niobium, crystal structure
Pages: 779-782

Abstract

By the high-temperature reaction of Nb2S4Br4 and TlBr a thallium salt of the anionic cluster complex [Nb2S4Br8]4- is obtained. Its crystal structure is determined by X-ray structural analysis. The complex is also characterized by Raman spectroscopy and electrospray-mass-spectrometry.