CRYSTAL STRUCTURE OF K2[Mo3(PdPPh3)S4(C2O4)3(H2O)3]в‹…0.5H2O
A. L. Gushchin, M. N. Sokolov, D. Y. Naumov, V. P. Fedin
Keywords: molybdenum, palladium, chalcogenide clusters, cuboidal clusters, X-ray analysis
Pages: 775-778
Abstract
By the reaction of [Mo3S4(C2O4)3(H2O)3]2- with PdCl2 and NH4H2PO2 as a reducing agent, followed by the addition of PPh3, a new oxalate cuboidal cluster complex [Mo3(PdPPh3)S4(C2O4)3(H2O)3]2- is obtained. It was isolated and structurally characterized as K2[Mo3(PdPPh3)S4(C2O4)3(H2O)3]⋅0.5H2O.
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