MOLECULAR STRUCTURE OF OCTACHLOROTRISILANE Si3Cl8
Y. S. Ezhov, S. A. Komarov, E. P. Simonenko, V. G. Sevast'yanov
Keywords: gas-phase electron diffraction, quantum chemistry, octachlorotrisilane, molecular structure, internal rotation
Pages: 633-639
Abstract
The parameters of the geometrical configuration of octachlorotrisilane Si3Cl8 were determined by quantum-chemical and gas-phase electron diffraction methods at 303±2 K. The calculated barrier to the internal rotation of SiCl3 groups relative to the Si-Si bond was calculated.
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