IR SPECTROSCOPY INVESTIGATION OF MOLECULAR ASSOCIATION IN THE ACETONE-TRICHLORMETHANE MIXTURE
M. T. Khatmullina, L. V. Rabchuk, V. V. Lazarev, A. S. Krauze
Keywords: acetone (AC), trichloromethane (TM), association, hydrogen bond, integral absorption coefficient (?), integral molar absorption coefficient
Pages: 490-494
Abstract
A significant increase in the stretching band intensity of trichloromethane in IR spectra of its solutions in acetone with increasing acetone mole fraction indicates the formation of hydrogen bonds between their molecules. The integral absorption coefficient (α) of this vibration is calculated. Experimental values of α are approximated by a theoretical dependence using the nonlinear least-squares method; association parameters are obtained. The relative volume fractions of H-bonded and free trichloromethane molecules are calculated depending on the total trichloromethane volume fraction in solution. The structure of the H-bonded associate is determined by quantum chemical calculations.
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